Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biol...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien |
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todo:paper_20444753_v7_n11_p2274_Yerien2023-10-03T16:38:09Z Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI. © 2017 The Royal Society of Chemistry. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds |
spellingShingle |
Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
topic_facet |
Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds |
description |
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI. © 2017 The Royal Society of Chemistry. |
format |
JOUR |
author |
Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. |
author_facet |
Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. |
author_sort |
Yerien, D.E. |
title |
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
title_short |
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
title_full |
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
title_fullStr |
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
title_full_unstemmed |
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator |
title_sort |
electron-catalyzed radical perfluoroalkylation of organic sulfides: the serendipitous use of the tmeda/i2 complex as a radical initiator |
url |
http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien |
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