Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator

Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biol...

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Autores principales:	Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L., Postigo, A.
Formato:	JOUR
Materias:	Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_20444753_v7_n11_p2274_Yerien
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spelling	todo:paper_20444753_v7_n11_p2274_Yerien2023-10-03T16:38:09Z Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI. © 2017 The Royal Society of Chemistry. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds
spellingShingle	Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A. Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
topic_facet	Electron donors Environmentally benign Organic sulfides Perfluoroalkylation Radical initiators Radical perfluoroalkylation Visible light Sulfur compounds
description	Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI. © 2017 The Royal Society of Chemistry.
format	JOUR
author	Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A.
author_facet	Yerien, D.E. Barata-Vallejo, S. Camps, B. Cristófalo, A.E. Cano, M.E. Uhrig, M.L. Postigo, A.
author_sort	Yerien, D.E.
title	Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
title_short	Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
title_full	Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
title_fullStr	Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
title_full_unstemmed	Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
title_sort	electron-catalyzed radical perfluoroalkylation of organic sulfides: the serendipitous use of the tmeda/i2 complex as a radical initiator
url	http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien
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Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator

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