A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in whic...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
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todo:paper_14337851_v48_n49_p9366_Albores2023-10-03T16:14:12Z A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine Alborés, P. Rentschler, E. Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds |
spellingShingle |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds Alborés, P. Rentschler, E. A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
topic_facet |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds |
description |
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,. |
format |
JOUR |
author |
Alborés, P. Rentschler, E. |
author_facet |
Alborés, P. Rentschler, E. |
author_sort |
Alborés, P. |
title |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
title_short |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
title_full |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
title_fullStr |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
title_full_unstemmed |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
title_sort |
co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
url |
http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
work_keys_str_mv |
AT alboresp aco36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine AT rentschlere aco36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine AT alboresp co36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine AT rentschlere co36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine |
_version_ |
1782025177387761664 |