A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine

A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in whic...

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Autores principales: Alborés, P., Rentschler, E.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores
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spelling todo:paper_14337851_v48_n49_p9366_Albores2023-10-03T16:14:12Z A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine Alborés, P. Rentschler, E. Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Cluster compounds
Cobalt
Dicarboxypyrazine
Magnetic properties
Chemical equations
Cluster compounds
Dinuclear
Mixed-valent compounds
Spin ground state
Chemical reactions
Cobalt
Magnetic properties
Cobalt compounds
spellingShingle Cluster compounds
Cobalt
Dicarboxypyrazine
Magnetic properties
Chemical equations
Cluster compounds
Dinuclear
Mixed-valent compounds
Spin ground state
Chemical reactions
Cobalt
Magnetic properties
Cobalt compounds
Alborés, P.
Rentschler, E.
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
topic_facet Cluster compounds
Cobalt
Dicarboxypyrazine
Magnetic properties
Chemical equations
Cluster compounds
Dinuclear
Mixed-valent compounds
Spin ground state
Chemical reactions
Cobalt
Magnetic properties
Cobalt compounds
description A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,.
format JOUR
author Alborés, P.
Rentschler, E.
author_facet Alborés, P.
Rentschler, E.
author_sort Alborés, P.
title A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
title_short A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
title_full A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
title_fullStr A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
title_full_unstemmed A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
title_sort co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
url http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores
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AT rentschlere aco36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine
AT alboresp co36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine
AT rentschlere co36clusterassembledfromthereactionofcobaltpivalatewith23dicarboxypyrazine
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