Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano |
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paperaa:paper_14246376_v2005_n12_p268_Giordano2023-06-12T16:50:11Z Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) Arkivoc 2006;2005(12):268-281 Giordano, L. Vermeij, R.J. Jares-Erijman, E.A. Diheteroarylethenes FRET Indole derivatives Photochromism Synthesis This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors. Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
language |
Inglés |
orig_language_str_mv |
eng |
topic |
Diheteroarylethenes FRET Indole derivatives Photochromism Synthesis |
spellingShingle |
Diheteroarylethenes FRET Indole derivatives Photochromism Synthesis Giordano, L. Vermeij, R.J. Jares-Erijman, E.A. Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
topic_facet |
Diheteroarylethenes FRET Indole derivatives Photochromism Synthesis |
description |
This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors. |
format |
Artículo Artículo publishedVersion |
author |
Giordano, L. Vermeij, R.J. Jares-Erijman, E.A. |
author_facet |
Giordano, L. Vermeij, R.J. Jares-Erijman, E.A. |
author_sort |
Giordano, L. |
title |
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
title_short |
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
title_full |
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
title_fullStr |
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
title_full_unstemmed |
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) |
title_sort |
synthesis of indole-containing diheteroarylethenes. new probes for photochromic fret (pcfret) |
publishDate |
2006 |
url |
http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano |
work_keys_str_mv |
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_version_ |
1769810349122387968 |