Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)

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This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading...

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Detalles Bibliográficos
Autores principales: Giordano, L., Vermeij, R.J., Jares-Erijman, E.A.
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: 2006
Materias:
Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paperaa:paper_14246376_v2005_n12_p268_Giordano2023-06-12T16:50:11Z Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET) Arkivoc 2006;2005(12):268-281 Giordano, L. Vermeij, R.J. Jares-Erijman, E.A. Diheteroarylethenes FRET Indole derivatives Photochromism Synthesis This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors. Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
language Inglés
orig_language_str_mv eng
topic Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
spellingShingle Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
Giordano, L.
Vermeij, R.J.
Jares-Erijman, E.A.
Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
topic_facet Diheteroarylethenes
FRET
Indole derivatives
Photochromism
Synthesis
description This paper reports a synthesis of novel diheteroarylethenes functionalized for coupling to biomolecules starting from indole derivatives. The strategy is based on the derivatization at the N-atom in the indole substructure. TBDMS protection proved to be superior over BOC protection schemes, leading to higher yields in the overall synthesis. The suitability of the new derivatives as acceptors for pcFRET was calculated for selected donors.
format Artículo
Artículo
publishedVersion
author Giordano, L.
Vermeij, R.J.
Jares-Erijman, E.A.
author_facet Giordano, L.
Vermeij, R.J.
Jares-Erijman, E.A.
author_sort Giordano, L.
title Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_short Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_full Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_fullStr Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_full_unstemmed Synthesis of indole-containing diheteroarylethenes. New probes for photochromic FRET (pcFRET)
title_sort synthesis of indole-containing diheteroarylethenes. new probes for photochromic fret (pcfret)
publishDate 2006
url http://hdl.handle.net/20.500.12110/paper_14246376_v2005_n12_p268_Giordano
work_keys_str_mv AT giordanol synthesisofindolecontainingdiheteroarylethenesnewprobesforphotochromicfretpcfret
AT vermeijrj synthesisofindolecontainingdiheteroarylethenesnewprobesforphotochromicfretpcfret
AT jareserijmanea synthesisofindolecontainingdiheteroarylethenesnewprobesforphotochromicfretpcfret
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