Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation

Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stab...

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Autores principales: Soria, Marcelo Abel, Fissore, Eliana Noemí, Rojas, Ana María Luisa
Publicado: 2016
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02608774_v175_n_p1_DeNobili
http://hdl.handle.net/20.500.12110/paper_02608774_v175_n_p1_DeNobili
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spelling paper:paper_02608774_v175_n_p1_DeNobili2023-06-08T15:22:21Z Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation Soria, Marcelo Abel Fissore, Eliana Noemí Rojas, Ana María Luisa Alginate copolymer Antioxidant films Ascorbic acid hydrolysis Citric acid Glycerol Alginate Antioxidants Citric acid Food preservation Food storage Glycerol Interfaces (materials) Organic acids Acid hydrolysis Antioxidant films Copolymer compositions Glycerol (plasticizer) Hydrolytic stability L(+)-ascorbic acid Polymeric networks Water penetration Ascorbic acid Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stability and, hence, the antioxidant half-life of films. Glycerol can facilitate the water penetration from the environment into the polymeric network. The CA content did not vary during film storage. Film browning was then associated to AA degradation. However, CA slowed down the browning development at longer storage times because of the changes in the kinetic order. It may catalyze the formation of unstable color compounds. The present work permitted to determine that AA and CA were 100% recovered after film casting. Also, it allowed finding the adequate film composition and period where the alginate film supporting AA and CA can be used as an antioxidant active interface for food preservation. © 2015 Published by Elsevier Ltd. Fil:Soria, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fissore, E.N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Rojas, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02608774_v175_n_p1_DeNobili http://hdl.handle.net/20.500.12110/paper_02608774_v175_n_p1_DeNobili
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Alginate copolymer
Antioxidant films
Ascorbic acid hydrolysis
Citric acid
Glycerol
Alginate
Antioxidants
Citric acid
Food preservation
Food storage
Glycerol
Interfaces (materials)
Organic acids
Acid hydrolysis
Antioxidant films
Copolymer compositions
Glycerol (plasticizer)
Hydrolytic stability
L(+)-ascorbic acid
Polymeric networks
Water penetration
Ascorbic acid
spellingShingle Alginate copolymer
Antioxidant films
Ascorbic acid hydrolysis
Citric acid
Glycerol
Alginate
Antioxidants
Citric acid
Food preservation
Food storage
Glycerol
Interfaces (materials)
Organic acids
Acid hydrolysis
Antioxidant films
Copolymer compositions
Glycerol (plasticizer)
Hydrolytic stability
L(+)-ascorbic acid
Polymeric networks
Water penetration
Ascorbic acid
Soria, Marcelo Abel
Fissore, Eliana Noemí
Rojas, Ana María Luisa
Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
topic_facet Alginate copolymer
Antioxidant films
Ascorbic acid hydrolysis
Citric acid
Glycerol
Alginate
Antioxidants
Citric acid
Food preservation
Food storage
Glycerol
Interfaces (materials)
Organic acids
Acid hydrolysis
Antioxidant films
Copolymer compositions
Glycerol (plasticizer)
Hydrolytic stability
L(+)-ascorbic acid
Polymeric networks
Water penetration
Ascorbic acid
description Alginate of known copolymer composition was applied to antioxidant film developed by loading L-(+)-ascorbic (AA) and citric (CA) acids. Relative humidity (RH, 33.3-75.2%) of storage (25.0 °C) and glycerol (plasticizer) level, separately and through their interaction, decreased the AA hydrolytic stability and, hence, the antioxidant half-life of films. Glycerol can facilitate the water penetration from the environment into the polymeric network. The CA content did not vary during film storage. Film browning was then associated to AA degradation. However, CA slowed down the browning development at longer storage times because of the changes in the kinetic order. It may catalyze the formation of unstable color compounds. The present work permitted to determine that AA and CA were 100% recovered after film casting. Also, it allowed finding the adequate film composition and period where the alginate film supporting AA and CA can be used as an antioxidant active interface for food preservation. © 2015 Published by Elsevier Ltd.
author Soria, Marcelo Abel
Fissore, Eliana Noemí
Rojas, Ana María Luisa
author_facet Soria, Marcelo Abel
Fissore, Eliana Noemí
Rojas, Ana María Luisa
author_sort Soria, Marcelo Abel
title Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
title_short Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
title_full Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
title_fullStr Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
title_full_unstemmed Stability of L-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
title_sort stability of l-(+)-ascorbic acid in alginate edible films loaded with citric acid for antioxidant food preservation
publishDate 2016
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02608774_v175_n_p1_DeNobili
http://hdl.handle.net/20.500.12110/paper_02608774_v175_n_p1_DeNobili
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AT fissoreeliananoemi stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation
AT rojasanamarialuisa stabilityoflascorbicacidinalginateediblefilmsloadedwithcitricacidforantioxidantfoodpreservation
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