Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalys...
Guardado en:
| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2001
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/35055 http://www.mdpi.com/1420-3049/6/12/1006 |
| Aporte de: |
| id |
I19-R120-10915-35055 |
|---|---|
| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Química heteropolyacids acid methoxymethyl ethers ester derivative phenols organic solvent phenol derivative protecting groups Well-Dawson catalyst silicon dioxide catalysis deprotection reaction |
| spellingShingle |
Ciencias Exactas Química heteropolyacids acid methoxymethyl ethers ester derivative phenols organic solvent phenol derivative protecting groups Well-Dawson catalyst silicon dioxide catalysis deprotection reaction Romanelli, Gustavo Pablo Autino, Juan Carlos Baronetti, Graciela T. Thomas, Horacio J. Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| topic_facet |
Ciencias Exactas Química heteropolyacids acid methoxymethyl ethers ester derivative phenols organic solvent phenol derivative protecting groups Well-Dawson catalyst silicon dioxide catalysis deprotection reaction |
| description |
Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable. |
| format |
Articulo Articulo |
| author |
Romanelli, Gustavo Pablo Autino, Juan Carlos Baronetti, Graciela T. Thomas, Horacio J. |
| author_facet |
Romanelli, Gustavo Pablo Autino, Juan Carlos Baronetti, Graciela T. Thomas, Horacio J. |
| author_sort |
Romanelli, Gustavo Pablo |
| title |
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| title_short |
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| title_full |
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| title_fullStr |
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| title_full_unstemmed |
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure |
| title_sort |
efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with wells-dawson structure |
| publishDate |
2001 |
| url |
http://sedici.unlp.edu.ar/handle/10915/35055 http://www.mdpi.com/1420-3049/6/12/1006 |
| work_keys_str_mv |
AT romanelligustavopablo efficientdeprotectionofphenolmethoxymethylethersusingasolidacidcatalystwithwellsdawsonstructure AT autinojuancarlos efficientdeprotectionofphenolmethoxymethylethersusingasolidacidcatalystwithwellsdawsonstructure AT baronettigracielat efficientdeprotectionofphenolmethoxymethylethersusingasolidacidcatalystwithwellsdawsonstructure AT thomashoracioj efficientdeprotectionofphenolmethoxymethylethersusingasolidacidcatalystwithwellsdawsonstructure |
| bdutipo_str |
Repositorios |
| _version_ |
1764820470780133376 |