Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer

The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are...

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Autores principales: Lezna, Reynaldo Oscar, Romagnoli, Roberto, Tacconi, Norma R. de, Rajeshwar, Krishnan
Formato: Articulo
Lenguaje:Inglés
Publicado: 2002
Materias:
Química
cobalt
spectroelectrochemistry
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/170893
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-170893
record_format dspace
spelling I19-R120-10915-1708932024-10-01T04:12:44Z http://sedici.unlp.edu.ar/handle/10915/170893 Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer Lezna, Reynaldo Oscar Romagnoli, Roberto Tacconi, Norma R. de Rajeshwar, Krishnan 2002 2024-09-30T17:56:34Z en Química cobalt spectroelectrochemistry The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy. Centro de Investigación y Desarrollo en Tecnología de Pinturas Articulo Articulo http://creativecommons.org/licenses/by-nc-nd/4.0/ Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) application/pdf 3612-3621
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
cobalt
spectroelectrochemistry
spellingShingle Química
cobalt
spectroelectrochemistry
Lezna, Reynaldo Oscar
Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
topic_facet Química
cobalt
spectroelectrochemistry
description The cobalt hexacyanoferrate system, Mh [FeB(CN)6]l, (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.
format Articulo
Articulo
author Lezna, Reynaldo Oscar
Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
author_facet Lezna, Reynaldo Oscar
Romagnoli, Roberto
Tacconi, Norma R. de
Rajeshwar, Krishnan
author_sort Lezna, Reynaldo Oscar
title Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_short Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_full Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_fullStr Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_full_unstemmed Cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
title_sort cobalt hexacyanoferrate: compound stoichiometry, infrared spectroelectrochemistry and photoinduced electron transfer
publishDate 2002
url http://sedici.unlp.edu.ar/handle/10915/170893
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AT tacconinormarde cobalthexacyanoferratecompoundstoichiometryinfraredspectroelectrochemistryandphotoinducedelectrontransfer
AT rajeshwarkrishnan cobalthexacyanoferratecompoundstoichiometryinfraredspectroelectrochemistryandphotoinducedelectrontransfer
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