Photophysical properties of porphycene derivatives (18 π porphyrinoids)
Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of...
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1997
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/159379 |
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I19-R120-10915-1593792023-10-27T04:06:51Z http://sedici.unlp.edu.ar/handle/10915/159379 Photophysical properties of porphycene derivatives (18 π porphyrinoids) Braslavsky, Silvia E. Müller, Martin Mártire, Daniel Osvaldo Pörting, Sigrid Bertolotti, Sonia G. Chakravorti, Sankar Koç-Weier, Gül Knipp, Bernd Schaffner, Kurt 1997 2023-10-26T12:15:58Z en Química Porphyrins Photodynamic therapy Triplet Singlet oxygen Sensitization Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of fluorescence and O₂(¹∆g) sensitization qualify most of these porphycenes as potential photodynamic therapy agents (so-called second-generation sensitizers), unless steric or electronic effects by substitution perturb the parent aromatic 18 π system. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Articulo Articulo http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 191-198 |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Química Porphyrins Photodynamic therapy Triplet Singlet oxygen Sensitization |
spellingShingle |
Química Porphyrins Photodynamic therapy Triplet Singlet oxygen Sensitization Braslavsky, Silvia E. Müller, Martin Mártire, Daniel Osvaldo Pörting, Sigrid Bertolotti, Sonia G. Chakravorti, Sankar Koç-Weier, Gül Knipp, Bernd Schaffner, Kurt Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
topic_facet |
Química Porphyrins Photodynamic therapy Triplet Singlet oxygen Sensitization |
description |
Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of fluorescence and O₂(¹∆g) sensitization qualify most of these porphycenes as potential photodynamic therapy agents (so-called second-generation sensitizers), unless steric or electronic effects by substitution perturb the parent aromatic 18 π system. |
format |
Articulo Articulo |
author |
Braslavsky, Silvia E. Müller, Martin Mártire, Daniel Osvaldo Pörting, Sigrid Bertolotti, Sonia G. Chakravorti, Sankar Koç-Weier, Gül Knipp, Bernd Schaffner, Kurt |
author_facet |
Braslavsky, Silvia E. Müller, Martin Mártire, Daniel Osvaldo Pörting, Sigrid Bertolotti, Sonia G. Chakravorti, Sankar Koç-Weier, Gül Knipp, Bernd Schaffner, Kurt |
author_sort |
Braslavsky, Silvia E. |
title |
Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
title_short |
Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
title_full |
Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
title_fullStr |
Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
title_full_unstemmed |
Photophysical properties of porphycene derivatives (18 π porphyrinoids) |
title_sort |
photophysical properties of porphycene derivatives (18 π porphyrinoids) |
publishDate |
1997 |
url |
http://sedici.unlp.edu.ar/handle/10915/159379 |
work_keys_str_mv |
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