Photophysical properties of porphycene derivatives (18 π porphyrinoids)

Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of...

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Autores principales: Braslavsky, Silvia E., Müller, Martin, Mártire, Daniel Osvaldo, Pörting, Sigrid, Bertolotti, Sonia G., Chakravorti, Sankar, Koç-Weier, Gül, Knipp, Bernd, Schaffner, Kurt
Formato: Articulo
Lenguaje:Inglés
Publicado: 1997
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/159379
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id I19-R120-10915-159379
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spelling I19-R120-10915-1593792023-10-27T04:06:51Z http://sedici.unlp.edu.ar/handle/10915/159379 Photophysical properties of porphycene derivatives (18 π porphyrinoids) Braslavsky, Silvia E. Müller, Martin Mártire, Daniel Osvaldo Pörting, Sigrid Bertolotti, Sonia G. Chakravorti, Sankar Koç-Weier, Gül Knipp, Bernd Schaffner, Kurt 1997 2023-10-26T12:15:58Z en Química Porphyrins Photodynamic therapy Triplet Singlet oxygen Sensitization Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of fluorescence and O₂(¹∆g) sensitization qualify most of these porphycenes as potential photodynamic therapy agents (so-called second-generation sensitizers), unless steric or electronic effects by substitution perturb the parent aromatic 18 π system. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Articulo Articulo http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 191-198
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Porphyrins
Photodynamic therapy
Triplet
Singlet oxygen
Sensitization
spellingShingle Química
Porphyrins
Photodynamic therapy
Triplet
Singlet oxygen
Sensitization
Braslavsky, Silvia E.
Müller, Martin
Mártire, Daniel Osvaldo
Pörting, Sigrid
Bertolotti, Sonia G.
Chakravorti, Sankar
Koç-Weier, Gül
Knipp, Bernd
Schaffner, Kurt
Photophysical properties of porphycene derivatives (18 π porphyrinoids)
topic_facet Química
Porphyrins
Photodynamic therapy
Triplet
Singlet oxygen
Sensitization
description Absorption and fluorescence spectral data and triplet energy content, as well as quantum yields of fluorescence, of triplet state formation, and of sensitized generation of singlet molecular oxygen, O₂(¹∆g), of 38 porphycene derivatives are reported. Long-wavelength absorption and the efficiency of fluorescence and O₂(¹∆g) sensitization qualify most of these porphycenes as potential photodynamic therapy agents (so-called second-generation sensitizers), unless steric or electronic effects by substitution perturb the parent aromatic 18 π system.
format Articulo
Articulo
author Braslavsky, Silvia E.
Müller, Martin
Mártire, Daniel Osvaldo
Pörting, Sigrid
Bertolotti, Sonia G.
Chakravorti, Sankar
Koç-Weier, Gül
Knipp, Bernd
Schaffner, Kurt
author_facet Braslavsky, Silvia E.
Müller, Martin
Mártire, Daniel Osvaldo
Pörting, Sigrid
Bertolotti, Sonia G.
Chakravorti, Sankar
Koç-Weier, Gül
Knipp, Bernd
Schaffner, Kurt
author_sort Braslavsky, Silvia E.
title Photophysical properties of porphycene derivatives (18 π porphyrinoids)
title_short Photophysical properties of porphycene derivatives (18 π porphyrinoids)
title_full Photophysical properties of porphycene derivatives (18 π porphyrinoids)
title_fullStr Photophysical properties of porphycene derivatives (18 π porphyrinoids)
title_full_unstemmed Photophysical properties of porphycene derivatives (18 π porphyrinoids)
title_sort photophysical properties of porphycene derivatives (18 π porphyrinoids)
publishDate 1997
url http://sedici.unlp.edu.ar/handle/10915/159379
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