Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its dep...
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Autores principales: | , , |
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Formato: | Articulo |
Lenguaje: | Alemán |
Publicado: |
1993
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Materias: | |
Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/146414 |
Aporte de: |
id |
I19-R120-10915-146414 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Alemán |
topic |
Química Vanadyl(IV) saccharinate IR spectra Electronic spectra Magnetic and thermal behaviour |
spellingShingle |
Química Vanadyl(IV) saccharinate IR spectra Electronic spectra Magnetic and thermal behaviour Ferrer, Evelina Gloria Etcheverry, Susana Beatriz Baran, Enrique José Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
topic_facet |
Química Vanadyl(IV) saccharinate IR spectra Electronic spectra Magnetic and thermal behaviour |
description |
The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated. |
format |
Articulo Articulo |
author |
Ferrer, Evelina Gloria Etcheverry, Susana Beatriz Baran, Enrique José |
author_facet |
Ferrer, Evelina Gloria Etcheverry, Susana Beatriz Baran, Enrique José |
author_sort |
Ferrer, Evelina Gloria |
title |
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
title_short |
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
title_full |
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
title_fullStr |
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
title_full_unstemmed |
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat |
title_sort |
darstellung und eigenschaften von vanadyl(iv)-saccharinat |
publishDate |
1993 |
url |
http://sedici.unlp.edu.ar/handle/10915/146414 |
work_keys_str_mv |
AT ferrerevelinagloria darstellungundeigenschaftenvonvanadylivsaccharinat AT etcheverrysusanabeatriz darstellungundeigenschaftenvonvanadylivsaccharinat AT baranenriquejose darstellungundeigenschaftenvonvanadylivsaccharinat |
bdutipo_str |
Repositorios |
_version_ |
1764820461193003009 |