Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis

A hydrous oxide film can be grown on a CO₅₀Ni₂₅SI₁₅B₁₀ amorphous alloy through the application of a periodic perturbing potential routine in alkaline solution. The optimal parameters of the square wave potential signal are determined. The oxide film is a precursor of a Co-Ni spinel as concluded from...

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Detalles Bibliográficos
Autores principales: Triaca, Walter Enrique, Arvia, Alejandro Jorge, Kessler, T.
Formato: Articulo
Lenguaje:Inglés
Publicado: 1993
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/145960
Aporte de:
id I19-R120-10915-145960
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Física
Oxide
Oxygen
Hydrous oxide
Catalytic activity
Oxide layer
spellingShingle Física
Oxide
Oxygen
Hydrous oxide
Catalytic activity
Oxide layer
Triaca, Walter Enrique
Arvia, Alejandro Jorge
Kessler, T.
Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
topic_facet Física
Oxide
Oxygen
Hydrous oxide
Catalytic activity
Oxide layer
description A hydrous oxide film can be grown on a CO₅₀Ni₂₅SI₁₅B₁₀ amorphous alloy through the application of a periodic perturbing potential routine in alkaline solution. The optimal parameters of the square wave potential signal are determined. The oxide film is a precursor of a Co-Ni spinel as concluded from voltammetry, i.r. spectroscopy, XPS and SEM micrography. The catalytic activity of the oxide layer for the oxygen evolution reaction is demonstrated.
format Articulo
Articulo
author Triaca, Walter Enrique
Arvia, Alejandro Jorge
Kessler, T.
author_facet Triaca, Walter Enrique
Arvia, Alejandro Jorge
Kessler, T.
author_sort Triaca, Walter Enrique
title Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
title_short Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
title_full Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
title_fullStr Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
title_full_unstemmed Electroformation of electrocatalytically active hydrous oxide layers on a Co-Ni amorphous alloy under pulsating electrolysis
title_sort electroformation of electrocatalytically active hydrous oxide layers on a co-ni amorphous alloy under pulsating electrolysis
publishDate 1993
url http://sedici.unlp.edu.ar/handle/10915/145960
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AT arviaalejandrojorge electroformationofelectrocatalyticallyactivehydrousoxidelayersonaconiamorphousalloyunderpulsatingelectrolysis
AT kesslert electroformationofelectrocatalyticallyactivehydrousoxidelayersonaconiamorphousalloyunderpulsatingelectrolysis
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