Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)

The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) A, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved...

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Detalles Bibliográficos
Autores principales:	González Baró, Ana Cecilia, Piro, Oscar Enrique, Parajón Costa, Beatriz Susana, Baran, Enrique José, Castellano, Eduardo Ernesto
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	1998
Materias:	Química Ciencias Exactas Vanadium(V) Inorganic etoxoester Crystal structure analysis Vibrational spectra Electronic spectra
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/140177
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-140177
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Química Ciencias Exactas Vanadium(V) Inorganic etoxoester Crystal structure analysis Vibrational spectra Electronic spectra
spellingShingle	Química Ciencias Exactas Vanadium(V) Inorganic etoxoester Crystal structure analysis Vibrational spectra Electronic spectra González Baró, Ana Cecilia Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José Castellano, Eduardo Ernesto Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
topic_facet	Química Ciencias Exactas Vanadium(V) Inorganic etoxoester Crystal structure analysis Vibrational spectra Electronic spectra
description	The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) A, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved employing 2902 independent reflections with I>2σ(I) by direct and Fourier methods and refined by a full-matrix least-squares fit to R; 1=0.049. Infrared and Raman spectra of the solid compound and the electronic absorption spectra of its acetonitrilic and ethanolic solutions were recorded and are briefly discussed.
format	Articulo Articulo
author	González Baró, Ana Cecilia Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José Castellano, Eduardo Ernesto
author_facet	González Baró, Ana Cecilia Piro, Oscar Enrique Parajón Costa, Beatriz Susana Baran, Enrique José Castellano, Eduardo Ernesto
author_sort	González Baró, Ana Cecilia
title	Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
title_short	Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
title_full	Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
title_fullStr	Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
title_full_unstemmed	Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
title_sort	crystal structure and spectroscopic behaviour of oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(v)
publishDate	1998
url	http://sedici.unlp.edu.ar/handle/10915/140177
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Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)

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