The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>

Compounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabili...

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Autores principales: Baran, Enrique José, Lavat, A. E., Saez Puche, R., Salinas Sanchez, A.
Formato: Articulo
Lenguaje:Inglés
Publicado: 1992
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/139138
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id I19-R120-10915-139138
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
spellingShingle Química
Baran, Enrique José
Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
topic_facet Química
description Compounds of general composition Ln2BaCuO5 (Ln=lanthanide) adopt different structural types. Two series of structures have been reported for LnzBaCuO5 compounds. For lanthanide ions smaller than Nd(III) (Y and Sm-Lu) the so-called "green phases" (orthorhombic, space group Pbnm) are stabilized. They are one of the main impurities generated during the synthesis of the LnBa2Cu3OT_x-type high-T¢ superconducting oxides. A different structural type (tetragonal, space group P4/mbm) becomes stabilized for Ln = La or Nd, although in the case of the lanthanum-containing material the totally stoichiometric composition does not seem to be attainable.
format Articulo
Articulo
author Baran, Enrique José
Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
author_facet Baran, Enrique José
Lavat, A. E.
Saez Puche, R.
Salinas Sanchez, A.
author_sort Baran, Enrique José
title The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_short The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_full The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_fullStr The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_full_unstemmed The vibrational spectrum of Nd<SUB>2</SUB>BaCuO<SUB>5</SUB>
title_sort vibrational spectrum of nd<sub>2</sub>bacuo<sub>5</sub>
publishDate 1992
url http://sedici.unlp.edu.ar/handle/10915/139138
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