Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative

H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved...

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Autores principales: Sánchez, Laura Mabel, Sathicq, Ángel Gabriel, Baronetti, Graciela Teresita, Thomas, Horacio Jorge, Romanelli, Gustavo Pablo
Formato: Articulo
Lenguaje:Inglés
Publicado: 2013
Materias:
Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/138848
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-138848
record_format dspace
spelling I19-R120-10915-1388482023-08-15T18:26:23Z http://sedici.unlp.edu.ar/handle/10915/138848 Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative Sánchez, Laura Mabel Sathicq, Ángel Gabriel Baronetti, Graciela Teresita Thomas, Horacio Jorge Romanelli, Gustavo Pablo 2013-10-12 2022-07-04T19:10:00Z en Química Ciencias Exactas Heteropolyacid Oxidation 1,4-dihydropyridine Hydrogen peroxide H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction. Centro de Investigación y Desarrollo en Ciencias Aplicadas Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico Articulo Articulo http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) application/pdf 172-180
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
spellingShingle Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
Sánchez, Laura Mabel
Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
topic_facet Química
Ciencias Exactas
Heteropolyacid
Oxidation
1,4-dihydropyridine
Hydrogen peroxide
description H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HWDV, a molar ratio 1,4-DHP:H2O2 (1:10) at reflux of acetonitrile. A conversion of 98.6 % is achieved in only 120 min of reaction.
format Articulo
Articulo
author Sánchez, Laura Mabel
Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author_facet Sánchez, Laura Mabel
Sathicq, Ángel Gabriel
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Romanelli, Gustavo Pablo
author_sort Sánchez, Laura Mabel
title Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_short Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_full Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_fullStr Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_full_unstemmed Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative
title_sort vanadium-substituted wells-dawson heteropolyacid as catalyst for liquid phase oxidation of 1,4-dihydropyridine derivative
publishDate 2013
url http://sedici.unlp.edu.ar/handle/10915/138848
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