Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms

Molecular design and preparation of redox active films displaying mesoscopic levels of organization represents one of the most actively pursued research areas in nanochemistry. These mesostructured materials are not only of great interest at the fundamental level because of their unique properties b...

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Detalles Bibliográficos
Autores principales:	Lorenzo, Agustín, Marmisollé, Waldemar Alejandro, Maza, Eliana María, Ceolín, Marcelo Raúl, Azzaroni, Omar
Formato:	Articulo Preprint
Lenguaje:	Inglés
Publicado:	2018
Materias:	Física Química Polyelectrolyte Electrochemical energy conversion Nanotechnology Nanochemistry Materials science Ionic bonding Nanoarchitectonics Polyaniline Polymer Lamellar structure
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/125275
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-125275
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Física Química Polyelectrolyte Electrochemical energy conversion Nanotechnology Nanochemistry Materials science Ionic bonding Nanoarchitectonics Polyaniline Polymer Lamellar structure
spellingShingle	Física Química Polyelectrolyte Electrochemical energy conversion Nanotechnology Nanochemistry Materials science Ionic bonding Nanoarchitectonics Polyaniline Polymer Lamellar structure Lorenzo, Agustín Marmisollé, Waldemar Alejandro Maza, Eliana María Ceolín, Marcelo Raúl Azzaroni, Omar Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
topic_facet	Física Química Polyelectrolyte Electrochemical energy conversion Nanotechnology Nanochemistry Materials science Ionic bonding Nanoarchitectonics Polyaniline Polymer Lamellar structure
description	Molecular design and preparation of redox active films displaying mesoscopic levels of organization represents one of the most actively pursued research areas in nanochemistry. These mesostructured materials are not only of great interest at the fundamental level because of their unique properties but they can also be employed for a wide range of applications such as electrocatalysts, electronic devices, and electrochemical energy conversion and storage. Herein, we introduce a simple and straightforward strategy to chemically modify electrode surfaces with self-assembled electroactive polyelectrolyte-surfactant complexes. These assemblies are composed of amino-appended polyaniline and monododecyl phosphate. The complexes were deposited by spin-coating and the films were characterized by spectroscopic and X-ray-based techniques: XRR, GISAXS, WAXS, and XPS. The films presented a well-defined lamellar structure, directed by the strong interaction between the phosphate groups and the positively charged amine groups in the polyelectrolyte. These films also displayed intrinsic electroactivity in both acidic and neutral solutions, showing that the polymer remains electroactive and ionic transport is still possible through the stratified and hydrophobic coatings. The stability and enhanced electroactivity in neutral solutions make these assembled films promising building blocks for the construction of nanostructured electrochemical platforms.
format	Articulo Preprint
author	Lorenzo, Agustín Marmisollé, Waldemar Alejandro Maza, Eliana María Ceolín, Marcelo Raúl Azzaroni, Omar
author_facet	Lorenzo, Agustín Marmisollé, Waldemar Alejandro Maza, Eliana María Ceolín, Marcelo Raúl Azzaroni, Omar
author_sort	Lorenzo, Agustín
title	Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
title_short	Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
title_full	Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
title_fullStr	Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
title_full_unstemmed	Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
title_sort	electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms
publishDate	2018
url	http://sedici.unlp.edu.ar/handle/10915/125275
work_keys_str_mv	AT lorenzoagustin electrochemicalnanoarchitectonicsthroughpolyaminobenzylaminedodecylphosphatecomplexesredoxactivityandmesoscopicorganizationinselfassemblednanofilms AT marmisollewaldemaralejandro electrochemicalnanoarchitectonicsthroughpolyaminobenzylaminedodecylphosphatecomplexesredoxactivityandmesoscopicorganizationinselfassemblednanofilms AT mazaelianamaria electrochemicalnanoarchitectonicsthroughpolyaminobenzylaminedodecylphosphatecomplexesredoxactivityandmesoscopicorganizationinselfassemblednanofilms AT ceolinmarceloraul electrochemicalnanoarchitectonicsthroughpolyaminobenzylaminedodecylphosphatecomplexesredoxactivityandmesoscopicorganizationinselfassemblednanofilms AT azzaroniomar electrochemicalnanoarchitectonicsthroughpolyaminobenzylaminedodecylphosphatecomplexesredoxactivityandmesoscopicorganizationinselfassemblednanofilms
bdutipo_str	Repositorios
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Electrochemical nanoarchitectonics through polyaminobenzylamine-dodecyl phosphate complexes: redox activity and mesoscopic organization in self-assembled nanofilms

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