Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum

The cathodic discharge of ammonium ion dissolved in DMSO solution on platinum electrodes in the temperature range from 25 to 44 °C yields ammonia and hydrogen at the ratio 2 : 1. The kinetics of the reaction was studied both under stationary and non-stationary conditions and reveals an influence of...

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Detalles Bibliográficos
Autores principales: Martínez, C., Arvia, Alejandro Jorge, Wargon, J. A
Formato: Articulo
Lenguaje:Inglés
Publicado: 1973
Materias:
Ciencias Exactas
Química
Cathodic discharge
Ammonium ion
DMSO
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/121896
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-121896
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Cathodic discharge
Ammonium ion
DMSO
spellingShingle Ciencias Exactas
Química
Cathodic discharge
Ammonium ion
DMSO
Martínez, C.
Arvia, Alejandro Jorge
Wargon, J. A
Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
topic_facet Ciencias Exactas
Química
Cathodic discharge
Ammonium ion
DMSO
description The cathodic discharge of ammonium ion dissolved in DMSO solution on platinum electrodes in the temperature range from 25 to 44 °C yields ammonia and hydrogen at the ratio 2 : 1. The kinetics of the reaction was studied both under stationary and non-stationary conditions and reveals an influence of the treatment of the electrode surface. The kinetic parameters were interpreted with a reaction mechanism involving the participation of adsorption competition between either solvent or impurity molecules and hydrogen atoms, assuming the recombination of these adatoms is rate determining.
format Articulo
Articulo
author Martínez, C.
Arvia, Alejandro Jorge
Wargon, J. A
author_facet Martínez, C.
Arvia, Alejandro Jorge
Wargon, J. A
author_sort Martínez, C.
title Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
title_short Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
title_full Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
title_fullStr Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
title_full_unstemmed Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
title_sort kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum
publishDate 1973
url http://sedici.unlp.edu.ar/handle/10915/121896
work_keys_str_mv AT martinezc kineticsofthecathodicdischargeofammoniumiondissolvedindimethylsulfoxideonplatinum
AT arviaalejandrojorge kineticsofthecathodicdischargeofammoniumiondissolvedindimethylsulfoxideonplatinum
AT wargonja kineticsofthecathodicdischargeofammoniumiondissolvedindimethylsulfoxideonplatinum
bdutipo_str Repositorios
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