A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine

The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are near...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Piro, Oscar Enrique, Zinczuk, Juan, Baran, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2008
Materias:
Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/120123
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-120123
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
spellingShingle Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
Piro, Oscar Enrique
Zinczuk, Juan
Baran, Enrique José
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
topic_facet Química
Pyridinium
Thiosaccharinate Thiosaccharin
Crystal Structure
Supramolecular Adduct
IR Spectra
description The crystal structure of pyridinium thiosaccharinate thiosaccharin, [HNC5H5]+ [(tsac)(Htsac)]− (Htsac = C7H5NO2S2, the thiosaccharin molecule), was determined by single-crystal X-ray diffraction. Both, the thiosaccharinate anion, the corresponding neutral molecule and the pyridinium cation are nearly planar and arranged in the solid state in an almost parallel fashion, hence giving rise to a layered supramolecular structure. The anion shows small but significant modifications in the bonding of the thioamide group as compared with the neutral molecule. The crystal is further stabilized by an extensive H-bonding network. The FTIR spectrum of the compound is briefly commented.
format Articulo
Articulo
author Piro, Oscar Enrique
Zinczuk, Juan
Baran, Enrique José
author_facet Piro, Oscar Enrique
Zinczuk, Juan
Baran, Enrique José
author_sort Piro, Oscar Enrique
title A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_short A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_full A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_fullStr A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_full_unstemmed A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Pyridine
title_sort new supramolecular assembly obtained by reaction between thiosaccharin and pyridine
publishDate 2008
url http://sedici.unlp.edu.ar/handle/10915/120123
work_keys_str_mv AT pirooscarenrique anewsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
AT zinczukjuan anewsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
AT baranenriquejose anewsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
AT pirooscarenrique newsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
AT zinczukjuan newsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
AT baranenriquejose newsupramolecularassemblyobtainedbyreactionbetweenthiosaccharinandpyridine
bdutipo_str Repositorios
_version_ 1764820449337802753

Ejemplares similares