Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reactio...
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Autores principales: | , , |
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Formato: | Articulo |
Lenguaje: | Inglés |
Publicado: |
1973
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119948 https://www.sciencedirect.com/science/article/abs/pii/0013468673800775 |
Aporte de: |
id |
I19-R120-10915-119948 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Exactas Química Hydrogen Nickel HCl-dimethylsulphoxide |
spellingShingle |
Ciencias Exactas Química Hydrogen Nickel HCl-dimethylsulphoxide Delgado, A. Posadas, Dionisio Arvia, Alejandro Jorge Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
topic_facet |
Ciencias Exactas Química Hydrogen Nickel HCl-dimethylsulphoxide |
description |
The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step. |
format |
Articulo Articulo |
author |
Delgado, A. Posadas, Dionisio Arvia, Alejandro Jorge |
author_facet |
Delgado, A. Posadas, Dionisio Arvia, Alejandro Jorge |
author_sort |
Delgado, A. |
title |
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
title_short |
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
title_full |
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
title_fullStr |
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
title_full_unstemmed |
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen |
title_sort |
electrode behaviour of nickel in hcl-dimethylsulphoxide solutions : i. the cathodic evolution of hydrogen |
publishDate |
1973 |
url |
http://sedici.unlp.edu.ar/handle/10915/119948 https://www.sciencedirect.com/science/article/abs/pii/0013468673800775 |
work_keys_str_mv |
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bdutipo_str |
Repositorios |
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1764820449105018882 |