Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen

The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reactio...

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Autores principales: Delgado, A., Posadas, Dionisio, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1973
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119948
https://www.sciencedirect.com/science/article/abs/pii/0013468673800775
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id I19-R120-10915-119948
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
spellingShingle Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
Delgado, A.
Posadas, Dionisio
Arvia, Alejandro Jorge
Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
topic_facet Ciencias Exactas
Química
Hydrogen
Nickel
HCl-dimethylsulphoxide
description The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step.
format Articulo
Articulo
author Delgado, A.
Posadas, Dionisio
Arvia, Alejandro Jorge
author_facet Delgado, A.
Posadas, Dionisio
Arvia, Alejandro Jorge
author_sort Delgado, A.
title Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_short Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_full Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_fullStr Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_full_unstemmed Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
title_sort electrode behaviour of nickel in hcl-dimethylsulphoxide solutions : i. the cathodic evolution of hydrogen
publishDate 1973
url http://sedici.unlp.edu.ar/handle/10915/119948
https://www.sciencedirect.com/science/article/abs/pii/0013468673800775
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AT posadasdionisio electrodebehaviourofnickelinhcldimethylsulphoxidesolutionsithecathodicevolutionofhydrogen
AT arviaalejandrojorge electrodebehaviourofnickelinhcldimethylsulphoxidesolutionsithecathodicevolutionofhydrogen
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