Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C

The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electro...

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Autores principales: Bolzan, J. A., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1970
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119387
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id I19-R120-10915-119387
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
spellingShingle Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
Bolzan, J. A.
Arvia, Alejandro Jorge
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
topic_facet Ciencias Exactas
Química
Hydrogen chloride
Dimethylsulphoxide
description The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum.
format Articulo
Articulo
author Bolzan, J. A.
Arvia, Alejandro Jorge
author_facet Bolzan, J. A.
Arvia, Alejandro Jorge
author_sort Bolzan, J. A.
title Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_short Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_full Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_fullStr Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_full_unstemmed Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
title_sort electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°c
publishDate 1970
url http://sedici.unlp.edu.ar/handle/10915/119387
work_keys_str_mv AT bolzanja electricalconductanceofhydrogenchlorideindimethylsulphoxideat25c
AT arviaalejandrojorge electricalconductanceofhydrogenchlorideindimethylsulphoxideat25c
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