Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electro...
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Autores principales: | , |
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Formato: | Articulo |
Lenguaje: | Inglés |
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1970
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119387 |
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I19-R120-10915-119387 |
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institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide |
spellingShingle |
Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide Bolzan, J. A. Arvia, Alejandro Jorge Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
topic_facet |
Ciencias Exactas Química Hydrogen chloride Dimethylsulphoxide |
description |
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum. |
format |
Articulo Articulo |
author |
Bolzan, J. A. Arvia, Alejandro Jorge |
author_facet |
Bolzan, J. A. Arvia, Alejandro Jorge |
author_sort |
Bolzan, J. A. |
title |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
title_short |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
title_full |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
title_fullStr |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
title_full_unstemmed |
Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C |
title_sort |
electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°c |
publishDate |
1970 |
url |
http://sedici.unlp.edu.ar/handle/10915/119387 |
work_keys_str_mv |
AT bolzanja electricalconductanceofhydrogenchlorideindimethylsulphoxideat25c AT arviaalejandrojorge electricalconductanceofhydrogenchlorideindimethylsulphoxideat25c |
bdutipo_str |
Repositorios |
_version_ |
1764820448361578501 |