Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>

When KSCN is added to molten NaNO<sub>3</sub> -KNO<sub>3</sub> eutectic within the range of 230-316°C, a complex and a relatively violent chemical reaction takes place until a KSCN concentration of ca. 1 mequiv KSCN/100 g eutectic has been added; further addition produces onl...

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Detalles Bibliográficos
Autores principales: Martins, María Elisa, Calandra, Alfredo J., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1974
Materias:
Ciencias Exactas
Química
Chemical reaction
Molten salts
KSCN
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/118224
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-118224
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Chemical reaction
Molten salts
KSCN
spellingShingle Ciencias Exactas
Química
Chemical reaction
Molten salts
KSCN
Martins, María Elisa
Calandra, Alfredo J.
Arvia, Alejandro Jorge
Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
topic_facet Ciencias Exactas
Química
Chemical reaction
Molten salts
KSCN
description When KSCN is added to molten NaNO<sub>3</sub> -KNO<sub>3</sub> eutectic within the range of 230-316°C, a complex and a relatively violent chemical reaction takes place until a KSCN concentration of ca. 1 mequiv KSCN/100 g eutectic has been added; further addition produces only a small residual chemical reaction. The reaction yields NO<sub>2</sub>, SO<sup>2</sup><sub>4</sub> ions and basic ionic species in the melt and NO<sub>2</sub>, CO<sub>2</sub>, (CN)<sub>2</sub>, N<sub>2</sub>O and minor quantities of other gaseous products. The reaction is interpreted in terms of ionic equilibria involving NO<sub></sub>, NO<sub>2</sub>, SCN, O<sup>2</sup><sub>2</sub>, O<sp>2</sup>, O<sub>2</sub> and O<sup>2-</sup> ions and O<sub>2</sub> as principal reacting species.
format Articulo
Articulo
author Martins, María Elisa
Calandra, Alfredo J.
Arvia, Alejandro Jorge
author_facet Martins, María Elisa
Calandra, Alfredo J.
Arvia, Alejandro Jorge
author_sort Martins, María Elisa
title Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
title_short Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
title_full Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
title_fullStr Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
title_full_unstemmed Some reactions occurring between KSCN and molten NANO<sub>3</sub>-KNO<sub>3</sub>
title_sort some reactions occurring between kscn and molten nano<sub>3</sub>-kno<sub>3</sub>
publishDate 1974
url http://sedici.unlp.edu.ar/handle/10915/118224
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AT calandraalfredoj somereactionsoccurringbetweenkscnandmoltennanosub3subknosub3sub
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bdutipo_str Repositorios
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