Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the...
| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/117142 |
| Aporte de: |
| id |
I19-R120-10915-117142 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Química crystal structure FTIR spectra FT-Raman spectra synthesis thallium(I) oxalate-oxalic acid |
| spellingShingle |
Química crystal structure FTIR spectra FT-Raman spectra synthesis thallium(I) oxalate-oxalic acid Piro, Oscar Enrique Echeverría, Gustavo Alberto González Baró, Ana Cecilia Baran, Enrique José Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| topic_facet |
Química crystal structure FTIR spectra FT-Raman spectra synthesis thallium(I) oxalate-oxalic acid |
| description |
The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed. |
| format |
Articulo Articulo |
| author |
Piro, Oscar Enrique Echeverría, Gustavo Alberto González Baró, Ana Cecilia Baran, Enrique José |
| author_facet |
Piro, Oscar Enrique Echeverría, Gustavo Alberto González Baró, Ana Cecilia Baran, Enrique José |
| author_sort |
Piro, Oscar Enrique |
| title |
Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| title_short |
Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| title_full |
Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| title_fullStr |
Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| title_full_unstemmed |
Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate |
| title_sort |
tl<sub>2</sub>c<sub>2</sub>o<sub>4</sub>·h<sub>2</sub>c<sub>2</sub>o<sub>4</sub>: a new crystalline form of thallium(i) oxalate |
| publishDate |
2015 |
| url |
http://sedici.unlp.edu.ar/handle/10915/117142 |
| work_keys_str_mv |
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| bdutipo_str |
Repositorios |
| _version_ |
1764820446922932224 |