Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup>
An isolated reaction intermediate in the desulfurization of thiones promoted by phosphanes is provided by the ylide derivative 3, which is obtained by thiophilic addition of PCy<sub>3</sub> to 2. Complex 2 is formed from the disulfide‐containing dimetallic complex 1 by scission of the S−...
Guardado en:
| Autores principales: | , , , , |
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| Formato: | Articulo Comunicacion |
| Lenguaje: | Inglés |
| Publicado: |
2001
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/104400 http://hdl.handle.net/11336/98686 https://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20010105)40:1%3C220::AID-ANIE220%3E3.0.CO;2-3 |
| Aporte de: |
| id |
I19-R120-10915-104400 |
|---|---|
| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Física Química manganese phosphanes sulfur ylides |
| spellingShingle |
Ciencias Exactas Física Química manganese phosphanes sulfur ylides Ruiz, Javier Ceroni, Mario Quinzani, Oscar Valentín Riera, Víctor Piro, Oscar Enrique Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| topic_facet |
Ciencias Exactas Física Química manganese phosphanes sulfur ylides |
| description |
An isolated reaction intermediate in the desulfurization of thiones promoted by phosphanes is provided by the ylide derivative 3, which is obtained by thiophilic addition of PCy<sub>3</sub> to 2. Complex 2 is formed from the disulfide‐containing dimetallic complex 1 by scission of the S−S bond. [Mn]=Mn(CO)<sub>4</sub>⁺, R=Ph. |
| format |
Articulo Comunicacion |
| author |
Ruiz, Javier Ceroni, Mario Quinzani, Oscar Valentín Riera, Víctor Piro, Oscar Enrique |
| author_facet |
Ruiz, Javier Ceroni, Mario Quinzani, Oscar Valentín Riera, Víctor Piro, Oscar Enrique |
| author_sort |
Ruiz, Javier |
| title |
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| title_short |
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| title_full |
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| title_fullStr |
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| title_full_unstemmed |
Reversible S-S Bond Breaking and Formation in Disulfide-containing Dinuclear Complexes of Mn<sup>I</sup> |
| title_sort |
reversible s-s bond breaking and formation in disulfide-containing dinuclear complexes of mn<sup>i</sup> |
| publishDate |
2001 |
| url |
http://sedici.unlp.edu.ar/handle/10915/104400 http://hdl.handle.net/11336/98686 https://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20010105)40:1%3C220::AID-ANIE220%3E3.0.CO;2-3 |
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AT ruizjavier reversiblessbondbreakingandformationindisulfidecontainingdinuclearcomplexesofmnsupisup AT ceronimario reversiblessbondbreakingandformationindisulfidecontainingdinuclearcomplexesofmnsupisup AT quinzanioscarvalentin reversiblessbondbreakingandformationindisulfidecontainingdinuclearcomplexesofmnsupisup AT rieravictor reversiblessbondbreakingandformationindisulfidecontainingdinuclearcomplexesofmnsupisup AT pirooscarenrique reversiblessbondbreakingandformationindisulfidecontainingdinuclearcomplexesofmnsupisup |
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Repositorios |
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1764820442234748929 |