Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin

The Argentine stretch of the del Plata basin crosses regions devoted to extensive and intensive agriculture mostly with chemical pest control. The utilization of pesticides in the region has increased 900% in the last two decades associated with the introduction of biotech crops and direct-seeding t...

Descripción completa

Detalles Bibliográficos
Autores principales: Etchegoyen, María Agustina, Ronco, Alicia Estela, Almada, Pablo, Abelando, Mariana, Marino, Damián José Gabriel
Formato: Articulo
Lenguaje:Inglés
Publicado: 2017
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/104003
Aporte de:
id I19-R120-10915-104003
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Biología
GC-μECD
Pesticide fate
Environmental partitioning
Water/sediment
spellingShingle Biología
GC-μECD
Pesticide fate
Environmental partitioning
Water/sediment
Etchegoyen, María Agustina
Ronco, Alicia Estela
Almada, Pablo
Abelando, Mariana
Marino, Damián José Gabriel
Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
topic_facet Biología
GC-μECD
Pesticide fate
Environmental partitioning
Water/sediment
description The Argentine stretch of the del Plata basin crosses regions devoted to extensive and intensive agriculture mostly with chemical pest control. The utilization of pesticides in the region has increased 900% in the last two decades associated with the introduction of biotech crops and direct-seeding techniques. Our objective was to study the occurrence, concentration, and fate of pesticides in surface water and bottom sediments of the principal tributaries and main watercourse of the Paraguay-Paraná River. We sampled 22 sites in the distal positions of the main affluents and main watercourse of the Paraná and report here results from two monitoring campaigns (2010–2012). Surface water and bottom sediments were analyzed according to standardized methods by matrix-solid-phase dispersion and liquid-liquid extraction, respectively. Twenty-three pesticide compounds were analyzed by gas chromatography. The results from both campaigns indicated a generalized but variable distribution in the concentrations detected throughout the basin. The ranges of total measured pesticide concentrations in water and sediments were, respectively, 0.004–6.62 μg/l and 0.16–221.3 μg/ kg dry weight. Endosulfans, cypermethrin, and chlorpyrifos were ubiquitous compounds in both environmental compartments and quantitatively the most relevant. All concentrations detected in water were over the recommended guidelines for the protection of aquatic biota. The partitioning indicated a higher affinity for the sediments. Agricultural activity is the source of pesticide-pollution loads, transported by tributaries that reach the main watercourse and alter the quality of the aquatic ecosystem.
format Articulo
Articulo
author Etchegoyen, María Agustina
Ronco, Alicia Estela
Almada, Pablo
Abelando, Mariana
Marino, Damián José Gabriel
author_facet Etchegoyen, María Agustina
Ronco, Alicia Estela
Almada, Pablo
Abelando, Mariana
Marino, Damián José Gabriel
author_sort Etchegoyen, María Agustina
title Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
title_short Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
title_full Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
title_fullStr Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
title_full_unstemmed Occurrence and fate of pesticides in the Argentine stretch of the Paraguay-Paraná basin
title_sort occurrence and fate of pesticides in the argentine stretch of the paraguay-paraná basin
publishDate 2017
url http://sedici.unlp.edu.ar/handle/10915/104003
work_keys_str_mv AT etchegoyenmariaagustina occurrenceandfateofpesticidesintheargentinestretchoftheparaguayparanabasin
AT roncoaliciaestela occurrenceandfateofpesticidesintheargentinestretchoftheparaguayparanabasin
AT almadapablo occurrenceandfateofpesticidesintheargentinestretchoftheparaguayparanabasin
AT abelandomariana occurrenceandfateofpesticidesintheargentinestretchoftheparaguayparanabasin
AT marinodamianjosegabriel occurrenceandfateofpesticidesintheargentinestretchoftheparaguayparanabasin
bdutipo_str Repositorios
_version_ 1764820441628672000