Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
The degradation of phenol was used as a model reaction to investigate the photocatalytic properties of cerium-doped (0.1 nominal atomic percent) TiO2 catalysts in the presence and in the absence of oxidants: persulfate (PS) or hydrogen peroxide (HP). Experiments were performed in batch reactors usin...
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Formato: | Articulo |
Lenguaje: | Inglés |
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2017
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/103373 |
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I19-R120-10915-103373 |
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institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Química Photocatalysis Dopedtitaniumdioxide Phenol Persulfate Solar exposure |
spellingShingle |
Química Photocatalysis Dopedtitaniumdioxide Phenol Persulfate Solar exposure Martin, Marcela Vanessa Ipiña Hernández, Adriana Villabrille, Paula Isabel Rosso, Janina Alejandra Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
topic_facet |
Química Photocatalysis Dopedtitaniumdioxide Phenol Persulfate Solar exposure |
description |
The degradation of phenol was used as a model reaction to investigate the photocatalytic properties of cerium-doped (0.1 nominal atomic percent) TiO2 catalysts in the presence and in the absence of oxidants: persulfate (PS) or hydrogen peroxide (HP). Experiments were performed in batch reactors using either artificial light (ultraviolet or visible) or solar exposure during spring–summer seasons in La Plata City (34.90° S, 57.92° W, 15 MASL). The formation of hydroquinone, catechol, and p-benzoquinone was observed in all the experiments. Additionally, for the experiments with PS (with or without catalyst), evidence of the formation of dimers and trimers was found. Total degradation of phenol (250 μM) was achieved with doped material and 7 mM of PS (two doses) after 3 h of solar exposure (H<sup>S</sup> <sub>UV, T</sub> = 2.9 ± 0.6 10<sup>5</sup> J m<sup>−2</sup>). |
format |
Articulo Articulo |
author |
Martin, Marcela Vanessa Ipiña Hernández, Adriana Villabrille, Paula Isabel Rosso, Janina Alejandra |
author_facet |
Martin, Marcela Vanessa Ipiña Hernández, Adriana Villabrille, Paula Isabel Rosso, Janina Alejandra |
author_sort |
Martin, Marcela Vanessa |
title |
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
title_short |
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
title_full |
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
title_fullStr |
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
title_full_unstemmed |
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation |
title_sort |
combination of sunlight, oxidants, and ce-doped tio<sub>2</sub> for phenol degradation |
publishDate |
2017 |
url |
http://sedici.unlp.edu.ar/handle/10915/103373 |
work_keys_str_mv |
AT martinmarcelavanessa combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation AT ipinahernandezadriana combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation AT villabrillepaulaisabel combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation AT rossojaninaalejandra combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation |
bdutipo_str |
Repositorios |
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1764820441893961728 |