Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation

The degradation of phenol was used as a model reaction to investigate the photocatalytic properties of cerium-doped (0.1 nominal atomic percent) TiO2 catalysts in the presence and in the absence of oxidants: persulfate (PS) or hydrogen peroxide (HP). Experiments were performed in batch reactors usin...

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Autores principales: Martin, Marcela Vanessa, Ipiña Hernández, Adriana, Villabrille, Paula Isabel, Rosso, Janina Alejandra
Formato: Articulo
Lenguaje:Inglés
Publicado: 2017
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/103373
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id I19-R120-10915-103373
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Photocatalysis
Dopedtitaniumdioxide
Phenol
Persulfate
Solar exposure
spellingShingle Química
Photocatalysis
Dopedtitaniumdioxide
Phenol
Persulfate
Solar exposure
Martin, Marcela Vanessa
Ipiña Hernández, Adriana
Villabrille, Paula Isabel
Rosso, Janina Alejandra
Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
topic_facet Química
Photocatalysis
Dopedtitaniumdioxide
Phenol
Persulfate
Solar exposure
description The degradation of phenol was used as a model reaction to investigate the photocatalytic properties of cerium-doped (0.1 nominal atomic percent) TiO2 catalysts in the presence and in the absence of oxidants: persulfate (PS) or hydrogen peroxide (HP). Experiments were performed in batch reactors using either artificial light (ultraviolet or visible) or solar exposure during spring–summer seasons in La Plata City (34.90° S, 57.92° W, 15 MASL). The formation of hydroquinone, catechol, and p-benzoquinone was observed in all the experiments. Additionally, for the experiments with PS (with or without catalyst), evidence of the formation of dimers and trimers was found. Total degradation of phenol (250 μM) was achieved with doped material and 7 mM of PS (two doses) after 3 h of solar exposure (H<sup>S</sup> <sub>UV, T</sub> = 2.9 ± 0.6 10<sup>5</sup> J m<sup>−2</sup>).
format Articulo
Articulo
author Martin, Marcela Vanessa
Ipiña Hernández, Adriana
Villabrille, Paula Isabel
Rosso, Janina Alejandra
author_facet Martin, Marcela Vanessa
Ipiña Hernández, Adriana
Villabrille, Paula Isabel
Rosso, Janina Alejandra
author_sort Martin, Marcela Vanessa
title Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
title_short Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
title_full Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
title_fullStr Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
title_full_unstemmed Combination of sunlight, oxidants, and Ce-doped TiO<SUB>2</SUB> for phenol degradation
title_sort combination of sunlight, oxidants, and ce-doped tio<sub>2</sub> for phenol degradation
publishDate 2017
url http://sedici.unlp.edu.ar/handle/10915/103373
work_keys_str_mv AT martinmarcelavanessa combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation
AT ipinahernandezadriana combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation
AT villabrillepaulaisabel combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation
AT rossojaninaalejandra combinationofsunlightoxidantsandcedopedtiosub2subforphenoldegradation
bdutipo_str Repositorios
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