Aqueous solubility of volatile nonelectrolytes

The solubilities of gases in water and their distribution between coexisting liquid and steam are of great interest for hydrothermal processes because gaseous solutes are usually present. For many geochemical and industrial processes in aqueous media, it is important to have a suitable formulation t...

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Autores principales: Fernández-Prini, R., Alvarez, J.L., Harvey, A.H.
Formato: CHAP
Materias:
Binary mixtures
Diffusion in gases
Equilibrium constants
Solubility
Thermoanalysis
Ambient conditions
Experimental methods
Hydrothermal process
Hydrothermal system
Industrial processs
Liquid-vapor coexistence curve
Thermo dynamic analysis
Thermodynamic state
Temperature
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_97800804_v_n_p73_FernandezPrini
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_97800804_v_n_p73_FernandezPrini2023-10-03T16:42:38Z Aqueous solubility of volatile nonelectrolytes Fernández-Prini, R. Alvarez, J.L. Harvey, A.H. Binary mixtures Diffusion in gases Equilibrium constants Solubility Thermoanalysis Ambient conditions Experimental methods Hydrothermal process Hydrothermal system Industrial processs Liquid-vapor coexistence curve Thermo dynamic analysis Thermodynamic state Temperature The solubilities of gases in water and their distribution between coexisting liquid and steam are of great interest for hydrothermal processes because gaseous solutes are usually present. For many geochemical and industrial processes in aqueous media, it is important to have a suitable formulation to describe the solubilities of gases over a wide range of temperatures and pressures. This chapter focuses on aqueous Henry's constants kH at high temperatures, as well as on the alternative description by means of the distribution equilibrium constant KD. These two quantities are easily determined from the experimental solubilities of gaseous solutes when the solvent is far from its critical point. The thermodynamic states along the liquid-vapor coexistence curve are particularly relevant to describe the solubility of slightly soluble gases in water. Hydrothermal systems often operate at total pressures above 5 MPa, while for many practical cases the partial pressure of the solute gas may be smaller than 0.1 MPa. Thus, the clear difference between the two fluid phases at ambient conditions is blurred to some extent in hydrothermal processes, and more so as the temperature approaches Tc1. A thorough thermodynamic analysis produces values of Henry's constant and of KD that depend only on temperature. The use of these quantities to answer questions about the concentration of gases in water or in steam at high temperature is simpler. The two experimental methods used to determine kH for volatile solutes are analytic and synthetic method. © Elsevier Ltd All rights reserved. CHAP info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_97800804_v_n_p73_FernandezPrini
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Binary mixtures
Diffusion in gases
Equilibrium constants
Solubility
Thermoanalysis
Ambient conditions
Experimental methods
Hydrothermal process
Hydrothermal system
Industrial processs
Liquid-vapor coexistence curve
Thermo dynamic analysis
Thermodynamic state
Temperature
spellingShingle Binary mixtures
Diffusion in gases
Equilibrium constants
Solubility
Thermoanalysis
Ambient conditions
Experimental methods
Hydrothermal process
Hydrothermal system
Industrial processs
Liquid-vapor coexistence curve
Thermo dynamic analysis
Thermodynamic state
Temperature
Fernández-Prini, R.
Alvarez, J.L.
Harvey, A.H.
Aqueous solubility of volatile nonelectrolytes
topic_facet Binary mixtures
Diffusion in gases
Equilibrium constants
Solubility
Thermoanalysis
Ambient conditions
Experimental methods
Hydrothermal process
Hydrothermal system
Industrial processs
Liquid-vapor coexistence curve
Thermo dynamic analysis
Thermodynamic state
Temperature
description The solubilities of gases in water and their distribution between coexisting liquid and steam are of great interest for hydrothermal processes because gaseous solutes are usually present. For many geochemical and industrial processes in aqueous media, it is important to have a suitable formulation to describe the solubilities of gases over a wide range of temperatures and pressures. This chapter focuses on aqueous Henry's constants kH at high temperatures, as well as on the alternative description by means of the distribution equilibrium constant KD. These two quantities are easily determined from the experimental solubilities of gaseous solutes when the solvent is far from its critical point. The thermodynamic states along the liquid-vapor coexistence curve are particularly relevant to describe the solubility of slightly soluble gases in water. Hydrothermal systems often operate at total pressures above 5 MPa, while for many practical cases the partial pressure of the solute gas may be smaller than 0.1 MPa. Thus, the clear difference between the two fluid phases at ambient conditions is blurred to some extent in hydrothermal processes, and more so as the temperature approaches Tc1. A thorough thermodynamic analysis produces values of Henry's constant and of KD that depend only on temperature. The use of these quantities to answer questions about the concentration of gases in water or in steam at high temperature is simpler. The two experimental methods used to determine kH for volatile solutes are analytic and synthetic method. © Elsevier Ltd All rights reserved.
format CHAP
author Fernández-Prini, R.
Alvarez, J.L.
Harvey, A.H.
author_facet Fernández-Prini, R.
Alvarez, J.L.
Harvey, A.H.
author_sort Fernández-Prini, R.
title Aqueous solubility of volatile nonelectrolytes
title_short Aqueous solubility of volatile nonelectrolytes
title_full Aqueous solubility of volatile nonelectrolytes
title_fullStr Aqueous solubility of volatile nonelectrolytes
title_full_unstemmed Aqueous solubility of volatile nonelectrolytes
title_sort aqueous solubility of volatile nonelectrolytes
url http://hdl.handle.net/20.500.12110/paper_97800804_v_n_p73_FernandezPrini
work_keys_str_mv AT fernandezprinir aqueoussolubilityofvolatilenonelectrolytes
AT alvarezjl aqueoussolubilityofvolatilenonelectrolytes
AT harveyah aqueoussolubilityofvolatilenonelectrolytes
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