A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity
The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to c...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
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todo:paper_20734360_v11_n2_p_LeonBoigues2023-10-03T16:39:11Z A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity León-Boigues, L. von Bilderling, C. Pietrasanta, L.I. Azzaroni, O. Giussi, J.M. Mijangos, C. Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young's modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture. © 2019 by the authors. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide |
| spellingShingle |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide León-Boigues, L. von Bilderling, C. Pietrasanta, L.I. Azzaroni, O. Giussi, J.M. Mijangos, C. A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| topic_facet |
Anodic aluminum oxide template Free radical copolymerization Swelling and mechanical properties Alumina Anodic oxidation Biomechanics Cell culture Drug delivery Elastic moduli Free radicals Isomers Mechanical properties Medical nanotechnology Molecular weight Nanopillars Tissue engineering Wetting Adaptive devices Anodic aluminum oxide template Butyl methacrylates Crucial parameters Free radical copolymerization Hydroxyethyl acrylate Nanopillar structures Swelling capacities Aluminum oxide |
| description |
The tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young's modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture. © 2019 by the authors. |
| format |
JOUR |
| author |
León-Boigues, L. von Bilderling, C. Pietrasanta, L.I. Azzaroni, O. Giussi, J.M. Mijangos, C. |
| author_facet |
León-Boigues, L. von Bilderling, C. Pietrasanta, L.I. Azzaroni, O. Giussi, J.M. Mijangos, C. |
| author_sort |
León-Boigues, L. |
| title |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_short |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_full |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_fullStr |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_full_unstemmed |
A patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| title_sort |
patterned butyl methacrylate-co-2-hydroxyethyl acrylate copolymer with softening surface and swelling capacity |
| url |
http://hdl.handle.net/20.500.12110/paper_20734360_v11_n2_p_LeonBoigues |
| work_keys_str_mv |
AT leonboiguesl apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT vonbilderlingc apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT pietrasantali apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT azzaronio apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT giussijm apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT mijangosc apatternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT leonboiguesl patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT vonbilderlingc patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT pietrasantali patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT azzaronio patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT giussijm patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity AT mijangosc patternedbutylmethacrylateco2hydroxyethylacrylatecopolymerwithsofteningsurfaceandswellingcapacity |
| _version_ |
1807321819587280896 |