Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion

A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. T...

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Detalles Bibliográficos
Autores principales: Harvey, M.A., Suarez, S., Zolotarev, P.N., Proserpio, D.M., Baggio, R.
Formato: JOUR
Materias:
crystal structure
hydrogen-bonded porous structures
sulfate bridge
topological analysis
Complexation
Coordination reactions
Crystal structure
Nickel
Nickel sulfates
Sulfur compounds
Topology
Coordination complex
Hydrogen-bonded structures
Porous structures
Reference frameworks
Three-dimensional structure
Title compounds
Topological analysis
Topological approach
Hydrogen bonds
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_20532296_v74_n3_p351_Harvey
record_format dspace
spelling todo:paper_20532296_v74_n3_p351_Harvey2023-10-03T16:39:03Z Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion Harvey, M.A. Suarez, S. Zolotarev, P.N. Proserpio, D.M. Baggio, R. crystal structure hydrogen-bonded porous structures sulfate bridge topological analysis Complexation Coordination reactions Crystal structure Nickel Nickel sulfates Sulfur compounds Topology Coordination complex Hydrogen-bonded structures Porous structures Reference frameworks Three-dimensional structure Title compounds Topological analysis Topological approach Hydrogen bonds A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches. © International Union of Crystallography, 2018. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic crystal structure
hydrogen-bonded porous structures
sulfate bridge
topological analysis
Complexation
Coordination reactions
Crystal structure
Nickel
Nickel sulfates
Sulfur compounds
Topology
Coordination complex
Hydrogen-bonded structures
Porous structures
Reference frameworks
Three-dimensional structure
Title compounds
Topological analysis
Topological approach
Hydrogen bonds
spellingShingle crystal structure
hydrogen-bonded porous structures
sulfate bridge
topological analysis
Complexation
Coordination reactions
Crystal structure
Nickel
Nickel sulfates
Sulfur compounds
Topology
Coordination complex
Hydrogen-bonded structures
Porous structures
Reference frameworks
Three-dimensional structure
Title compounds
Topological analysis
Topological approach
Hydrogen bonds
Harvey, M.A.
Suarez, S.
Zolotarev, P.N.
Proserpio, D.M.
Baggio, R.
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
topic_facet crystal structure
hydrogen-bonded porous structures
sulfate bridge
topological analysis
Complexation
Coordination reactions
Crystal structure
Nickel
Nickel sulfates
Sulfur compounds
Topology
Coordination complex
Hydrogen-bonded structures
Porous structures
Reference frameworks
Three-dimensional structure
Title compounds
Topological analysis
Topological approach
Hydrogen bonds
description A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches. © International Union of Crystallography, 2018.
format JOUR
author Harvey, M.A.
Suarez, S.
Zolotarev, P.N.
Proserpio, D.M.
Baggio, R.
author_facet Harvey, M.A.
Suarez, S.
Zolotarev, P.N.
Proserpio, D.M.
Baggio, R.
author_sort Harvey, M.A.
title Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_short Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_full Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_fullStr Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_full_unstemmed Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
title_sort topological study of diverse hydrogen-bonded patterns found in a system of a nickel(ii) complex and the sulfate anion
url http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey
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