Perfluoroalkylation reactions of (hetero)arenes
Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo |
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todo:paper_20462069_v5_n77_p62498_BarataVallejo2023-10-03T16:38:38Z Perfluoroalkylation reactions of (hetero)arenes Barata-Vallejo, S. Bonesi, S.M. Postigo, A. Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to claim a relevant role in functionalization reactions, as revealed by the interesting properties of arenes with large perfluoroalkyl chains. Methods for achieving Ar-R<inf>f</inf> bonding reactions can be classified into thermal and photochemical, which can in turn make use of transition metals or be non-metal catalyzed. Reactions are mainly radical in nature. Radical methods for introducing R<inf>f</inf> moieties into arenes have resulted as being the most popular and versatile options available to synthetic chemists. © The Royal Society of Chemistry 2015. Fil:Bonesi, S.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions |
| spellingShingle |
Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions Barata-Vallejo, S. Bonesi, S.M. Postigo, A. Perfluoroalkylation reactions of (hetero)arenes |
| topic_facet |
Aromatic compounds Substitution reactions Transition metals Bonding reactions Functionalization reactions Homolytic aromatic substitutions Perfluoroalkyl chains Perfluoroalkylation Synthetic chemists Synthetic methods Trifluoromethylation Photochemical reactions |
| description |
Perfluoroalkylation reactions of arenes have not been the subject of intense study as has been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic methods proposed for achieving homolytic aromatic substitution reactions with perfluoroalkyl moieties have begun to claim a relevant role in functionalization reactions, as revealed by the interesting properties of arenes with large perfluoroalkyl chains. Methods for achieving Ar-R<inf>f</inf> bonding reactions can be classified into thermal and photochemical, which can in turn make use of transition metals or be non-metal catalyzed. Reactions are mainly radical in nature. Radical methods for introducing R<inf>f</inf> moieties into arenes have resulted as being the most popular and versatile options available to synthetic chemists. © The Royal Society of Chemistry 2015. |
| format |
JOUR |
| author |
Barata-Vallejo, S. Bonesi, S.M. Postigo, A. |
| author_facet |
Barata-Vallejo, S. Bonesi, S.M. Postigo, A. |
| author_sort |
Barata-Vallejo, S. |
| title |
Perfluoroalkylation reactions of (hetero)arenes |
| title_short |
Perfluoroalkylation reactions of (hetero)arenes |
| title_full |
Perfluoroalkylation reactions of (hetero)arenes |
| title_fullStr |
Perfluoroalkylation reactions of (hetero)arenes |
| title_full_unstemmed |
Perfluoroalkylation reactions of (hetero)arenes |
| title_sort |
perfluoroalkylation reactions of (hetero)arenes |
| url |
http://hdl.handle.net/20.500.12110/paper_20462069_v5_n77_p62498_BarataVallejo |
| work_keys_str_mv |
AT baratavallejos perfluoroalkylationreactionsofheteroarenes AT bonesism perfluoroalkylationreactionsofheteroarenes AT postigoa perfluoroalkylationreactionsofheteroarenes |
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1807318915333750784 |