Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator

Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biol...

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Detalles Bibliográficos
Autores principales: Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L., Postigo, A.
Formato: JOUR
Materias:
Electron donors
Environmentally benign
Organic sulfides
Perfluoroalkylation
Radical initiators
Radical perfluoroalkylation
Visible light
Sulfur compounds
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_20444753_v7_n11_p2274_Yerien
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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