Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina

High concentrations of fluoride have negative effects on human health, and it is one of the most widespread contaminants in groundwater, having being found in high concentrations in different countries over the entire world. Fluoride concentrations exceeding the drinking water levels are very freque...

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Autores principales: Calvi, C., Martinez, D., Dapeña, C., Gutheim, F.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_18666280_v75_n6_p_Calvi
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spelling todo:paper_18666280_v75_n6_p_Calvi2023-10-03T16:33:41Z Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina Calvi, C. Martinez, D. Dapeña, C. Gutheim, F. Fluoride Hydrogeochemistry La Ballenera creek Saturation index calcite Calcite Calcium carbonate Catchments Fluorine compounds Groundwater Groundwater pollution Potable water Runoff Sediments Sodium bicarbonate Surface waters Water levels Calcite precipitation Carbonate concretion Fluoride Fluoride concentrations Groundwater concentrations Hydro geochemistries Saturation index Water composition Fluoride minerals baseflow calcite calcium carbonate catchment concentration (composition) fluoride groundwater pollution groundwater resource hydrogeochemistry pH precipitation (chemistry) Argentina Atlantic Ocean Buenos Aires [Argentina] Pampas High concentrations of fluoride have negative effects on human health, and it is one of the most widespread contaminants in groundwater, having being found in high concentrations in different countries over the entire world. Fluoride concentrations exceeding the drinking water levels are very frequent in the region known as Pampa Plain in Argentina, associated with loess-like sediments bearing volcanic shards and calcium carbonate concretions. In this study, the behavior of fluoride in the catchment of La Ballenera creek is performed to contribute to the understanding of the processes controlling its distribution at catchment scale. The catchment is around 100 km2, mostly in a flat landscape, outflowing into the Atlantic Ocean. The concentration of major ions, silica and fluoride was measured on 34 groundwater and 9 surface water samples obtained in October 2013. All the samples, both streamwater and groundwater, were sodium bicarbonate type with an average pH of 8 and 7.3, respectively. The fluoride concentrations in groundwater ranged between 1.1 and 2.5 mg/L with an average value of 1.9 mg/L. Fluoride concentrations in streamwater were close to groundwater concentrations indicating the predominance of baseflow on surface water composition. The variations in the contents of fluoride are due to two main factors, one geological–geomorphological and the other geochemical. The first one is related to the dominance of loess-like sediments formed by minerals bearing fluoride, and the second one is related to the control resulting on calcite precipitation adsorbing fluoride ions. © 2016, Springer-Verlag Berlin Heidelberg. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_18666280_v75_n6_p_Calvi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Fluoride
Hydrogeochemistry
La Ballenera creek
Saturation index calcite
Calcite
Calcium carbonate
Catchments
Fluorine compounds
Groundwater
Groundwater pollution
Potable water
Runoff
Sediments
Sodium bicarbonate
Surface waters
Water levels
Calcite precipitation
Carbonate concretion
Fluoride
Fluoride concentrations
Groundwater concentrations
Hydro geochemistries
Saturation index
Water composition
Fluoride minerals
baseflow
calcite
calcium carbonate
catchment
concentration (composition)
fluoride
groundwater pollution
groundwater resource
hydrogeochemistry
pH
precipitation (chemistry)
Argentina
Atlantic Ocean
Buenos Aires [Argentina]
Pampas
spellingShingle Fluoride
Hydrogeochemistry
La Ballenera creek
Saturation index calcite
Calcite
Calcium carbonate
Catchments
Fluorine compounds
Groundwater
Groundwater pollution
Potable water
Runoff
Sediments
Sodium bicarbonate
Surface waters
Water levels
Calcite precipitation
Carbonate concretion
Fluoride
Fluoride concentrations
Groundwater concentrations
Hydro geochemistries
Saturation index
Water composition
Fluoride minerals
baseflow
calcite
calcium carbonate
catchment
concentration (composition)
fluoride
groundwater pollution
groundwater resource
hydrogeochemistry
pH
precipitation (chemistry)
Argentina
Atlantic Ocean
Buenos Aires [Argentina]
Pampas
Calvi, C.
Martinez, D.
Dapeña, C.
Gutheim, F.
Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
topic_facet Fluoride
Hydrogeochemistry
La Ballenera creek
Saturation index calcite
Calcite
Calcium carbonate
Catchments
Fluorine compounds
Groundwater
Groundwater pollution
Potable water
Runoff
Sediments
Sodium bicarbonate
Surface waters
Water levels
Calcite precipitation
Carbonate concretion
Fluoride
Fluoride concentrations
Groundwater concentrations
Hydro geochemistries
Saturation index
Water composition
Fluoride minerals
baseflow
calcite
calcium carbonate
catchment
concentration (composition)
fluoride
groundwater pollution
groundwater resource
hydrogeochemistry
pH
precipitation (chemistry)
Argentina
Atlantic Ocean
Buenos Aires [Argentina]
Pampas
description High concentrations of fluoride have negative effects on human health, and it is one of the most widespread contaminants in groundwater, having being found in high concentrations in different countries over the entire world. Fluoride concentrations exceeding the drinking water levels are very frequent in the region known as Pampa Plain in Argentina, associated with loess-like sediments bearing volcanic shards and calcium carbonate concretions. In this study, the behavior of fluoride in the catchment of La Ballenera creek is performed to contribute to the understanding of the processes controlling its distribution at catchment scale. The catchment is around 100 km2, mostly in a flat landscape, outflowing into the Atlantic Ocean. The concentration of major ions, silica and fluoride was measured on 34 groundwater and 9 surface water samples obtained in October 2013. All the samples, both streamwater and groundwater, were sodium bicarbonate type with an average pH of 8 and 7.3, respectively. The fluoride concentrations in groundwater ranged between 1.1 and 2.5 mg/L with an average value of 1.9 mg/L. Fluoride concentrations in streamwater were close to groundwater concentrations indicating the predominance of baseflow on surface water composition. The variations in the contents of fluoride are due to two main factors, one geological–geomorphological and the other geochemical. The first one is related to the dominance of loess-like sediments formed by minerals bearing fluoride, and the second one is related to the control resulting on calcite precipitation adsorbing fluoride ions. © 2016, Springer-Verlag Berlin Heidelberg.
format JOUR
author Calvi, C.
Martinez, D.
Dapeña, C.
Gutheim, F.
author_facet Calvi, C.
Martinez, D.
Dapeña, C.
Gutheim, F.
author_sort Calvi, C.
title Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
title_short Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
title_full Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
title_fullStr Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
title_full_unstemmed Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina
title_sort abundance and distribution of fluoride concentrations in groundwater: la ballenera catchment, southeast of buenos aires province, argentina
url http://hdl.handle.net/20.500.12110/paper_18666280_v75_n6_p_Calvi
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AT dapenac abundanceanddistributionoffluorideconcentrationsingroundwaterlaballeneracatchmentsoutheastofbuenosairesprovinceargentina
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