Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca...
Guardado en:
Autores principales: | , , , |
---|---|
Formato: | JOUR |
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte |
Aporte de: |
id |
todo:paper_17434955_v7_n3_p215_FernandezSolarte |
---|---|
record_format |
dspace |
spelling |
todo:paper_17434955_v7_n3_p215_FernandezSolarte2023-10-03T16:31:21Z Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence Fernández Solarte, A.M. Fernández, M.A. Dos Santos Afonso, M. Torres Sánchez, R.M. Humic acid Montmorillonite Porosity Specific surface area Thermal treated montmorillonite The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca+2 or both were added, will help to better understand the surface behaviour of the binary or ternary systems. Calcium or HA adsorption produces a decrease of the Mt and Mt550 specific surface area (SSA). X-ray diffraction indicates calcium presence and no entrance of humic acid in the interlayer of Mt, while in the ternary systems (calcium-HA-Mt) a hindrance to the calcium entrance was observed. The opposite behaviour produces the adsorption of HA or calcium on electric charge of both samples. The mean pore diameter (MPD) for Mt increases with Ca+2 adsorption while no change was found after HA adsorption, in contrast to that found for Mt550. © 2015 Inderscience Enterprises Ltd. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Humic acid Montmorillonite Porosity Specific surface area Thermal treated montmorillonite |
spellingShingle |
Humic acid Montmorillonite Porosity Specific surface area Thermal treated montmorillonite Fernández Solarte, A.M. Fernández, M.A. Dos Santos Afonso, M. Torres Sánchez, R.M. Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
topic_facet |
Humic acid Montmorillonite Porosity Specific surface area Thermal treated montmorillonite |
description |
The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca+2 or both were added, will help to better understand the surface behaviour of the binary or ternary systems. Calcium or HA adsorption produces a decrease of the Mt and Mt550 specific surface area (SSA). X-ray diffraction indicates calcium presence and no entrance of humic acid in the interlayer of Mt, while in the ternary systems (calcium-HA-Mt) a hindrance to the calcium entrance was observed. The opposite behaviour produces the adsorption of HA or calcium on electric charge of both samples. The mean pore diameter (MPD) for Mt increases with Ca+2 adsorption while no change was found after HA adsorption, in contrast to that found for Mt550. © 2015 Inderscience Enterprises Ltd. |
format |
JOUR |
author |
Fernández Solarte, A.M. Fernández, M.A. Dos Santos Afonso, M. Torres Sánchez, R.M. |
author_facet |
Fernández Solarte, A.M. Fernández, M.A. Dos Santos Afonso, M. Torres Sánchez, R.M. |
author_sort |
Fernández Solarte, A.M. |
title |
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
title_short |
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
title_full |
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
title_fullStr |
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
title_full_unstemmed |
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence |
title_sort |
humic acid interaction with clay minerals. modification of the surface properties by calcium presence |
url |
http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte |
work_keys_str_mv |
AT fernandezsolarteam humicacidinteractionwithclaymineralsmodificationofthesurfacepropertiesbycalciumpresence AT fernandezma humicacidinteractionwithclaymineralsmodificationofthesurfacepropertiesbycalciumpresence AT dossantosafonsom humicacidinteractionwithclaymineralsmodificationofthesurfacepropertiesbycalciumpresence AT torressanchezrm humicacidinteractionwithclaymineralsmodificationofthesurfacepropertiesbycalciumpresence |
_version_ |
1782030855315652608 |