Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence

The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca...

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Autores principales: Fernández Solarte, A.M., Fernández, M.A., Dos Santos Afonso, M., Torres Sánchez, R.M.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte
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spelling todo:paper_17434955_v7_n3_p215_FernandezSolarte2023-10-03T16:31:21Z Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence Fernández Solarte, A.M. Fernández, M.A. Dos Santos Afonso, M. Torres Sánchez, R.M. Humic acid Montmorillonite Porosity Specific surface area Thermal treated montmorillonite The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca+2 or both were added, will help to better understand the surface behaviour of the binary or ternary systems. Calcium or HA adsorption produces a decrease of the Mt and Mt550 specific surface area (SSA). X-ray diffraction indicates calcium presence and no entrance of humic acid in the interlayer of Mt, while in the ternary systems (calcium-HA-Mt) a hindrance to the calcium entrance was observed. The opposite behaviour produces the adsorption of HA or calcium on electric charge of both samples. The mean pore diameter (MPD) for Mt increases with Ca+2 adsorption while no change was found after HA adsorption, in contrast to that found for Mt550. © 2015 Inderscience Enterprises Ltd. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Humic acid
Montmorillonite
Porosity
Specific surface area
Thermal treated montmorillonite
spellingShingle Humic acid
Montmorillonite
Porosity
Specific surface area
Thermal treated montmorillonite
Fernández Solarte, A.M.
Fernández, M.A.
Dos Santos Afonso, M.
Torres Sánchez, R.M.
Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
topic_facet Humic acid
Montmorillonite
Porosity
Specific surface area
Thermal treated montmorillonite
description The environmental importance of humic acid (HA) is mainly related to soil fertility, but it can also develop some human diseases by its intake as well as prevent calcium assimilation. Physicochemical characterisations of a montmorillonite (Mt) and its thermal treated product (Mt550), to which HA, Ca+2 or both were added, will help to better understand the surface behaviour of the binary or ternary systems. Calcium or HA adsorption produces a decrease of the Mt and Mt550 specific surface area (SSA). X-ray diffraction indicates calcium presence and no entrance of humic acid in the interlayer of Mt, while in the ternary systems (calcium-HA-Mt) a hindrance to the calcium entrance was observed. The opposite behaviour produces the adsorption of HA or calcium on electric charge of both samples. The mean pore diameter (MPD) for Mt increases with Ca+2 adsorption while no change was found after HA adsorption, in contrast to that found for Mt550. © 2015 Inderscience Enterprises Ltd.
format JOUR
author Fernández Solarte, A.M.
Fernández, M.A.
Dos Santos Afonso, M.
Torres Sánchez, R.M.
author_facet Fernández Solarte, A.M.
Fernández, M.A.
Dos Santos Afonso, M.
Torres Sánchez, R.M.
author_sort Fernández Solarte, A.M.
title Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
title_short Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
title_full Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
title_fullStr Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
title_full_unstemmed Humic acid interaction with clay minerals. Modification of the surface properties by calcium presence
title_sort humic acid interaction with clay minerals. modification of the surface properties by calcium presence
url http://hdl.handle.net/20.500.12110/paper_17434955_v7_n3_p215_FernandezSolarte
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