Photochromic relaxation kinetics

A new method for evaluating the rate constants of chemical reactions has been developed based on the differential photoconversion efficiencies of photochromic FRET acceptors incorporated into molecules on both sides of a chemical equilibrium. In the application of Photochromic Relaxation Kinetics (p...

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Autores principales: Jovin, T.M., Jares-Erijman, E.A.
Formato: JOUR
Materias:
PcFRET
Photochromism
Relaxation kinetics
Molecular dynamics
Rate constants
Thermodynamics
Chemical equilibrium
Photochromic Relaxation Kinetics (PcFRET)
Photoconversion efficiencies
Relaxation processes
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15421406_v430_n_p281_Jovin
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_15421406_v430_n_p281_Jovin
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spelling todo:paper_15421406_v430_n_p281_Jovin2023-10-03T16:22:57Z Photochromic relaxation kinetics Jovin, T.M. Jares-Erijman, E.A. PcFRET Photochromism Relaxation kinetics Molecular dynamics Photochromism Rate constants Thermodynamics Chemical equilibrium Photochromic Relaxation Kinetics (PcFRET) Photoconversion efficiencies Relaxation kinetics Relaxation processes A new method for evaluating the rate constants of chemical reactions has been developed based on the differential photoconversion efficiencies of photochromic FRET acceptors incorporated into molecules on both sides of a chemical equilibrium. In the application of Photochromic Relaxation Kinetics (pcRelKin) to a bimolecular binding reaction, one of the two interacting molecules bears a FRET donor and the second a photochromic acceptor. The close proximity required for FRET is achieved only in the complex. After photoconversion, the system exists in a thermo-dynamically asymmetric state, which relaxes according to first order kinetics. PcRelKin offers unique advantages over classical relaxation kinetics. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15421406_v430_n_p281_Jovin
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic PcFRET
Photochromism
Relaxation kinetics
Molecular dynamics
Photochromism
Rate constants
Thermodynamics
Chemical equilibrium
Photochromic Relaxation Kinetics (PcFRET)
Photoconversion efficiencies
Relaxation kinetics
Relaxation processes
spellingShingle PcFRET
Photochromism
Relaxation kinetics
Molecular dynamics
Photochromism
Rate constants
Thermodynamics
Chemical equilibrium
Photochromic Relaxation Kinetics (PcFRET)
Photoconversion efficiencies
Relaxation kinetics
Relaxation processes
Jovin, T.M.
Jares-Erijman, E.A.
Photochromic relaxation kinetics
topic_facet PcFRET
Photochromism
Relaxation kinetics
Molecular dynamics
Photochromism
Rate constants
Thermodynamics
Chemical equilibrium
Photochromic Relaxation Kinetics (PcFRET)
Photoconversion efficiencies
Relaxation kinetics
Relaxation processes
description A new method for evaluating the rate constants of chemical reactions has been developed based on the differential photoconversion efficiencies of photochromic FRET acceptors incorporated into molecules on both sides of a chemical equilibrium. In the application of Photochromic Relaxation Kinetics (pcRelKin) to a bimolecular binding reaction, one of the two interacting molecules bears a FRET donor and the second a photochromic acceptor. The close proximity required for FRET is achieved only in the complex. After photoconversion, the system exists in a thermo-dynamically asymmetric state, which relaxes according to first order kinetics. PcRelKin offers unique advantages over classical relaxation kinetics.
format JOUR
author Jovin, T.M.
Jares-Erijman, E.A.
author_facet Jovin, T.M.
Jares-Erijman, E.A.
author_sort Jovin, T.M.
title Photochromic relaxation kinetics
title_short Photochromic relaxation kinetics
title_full Photochromic relaxation kinetics
title_fullStr Photochromic relaxation kinetics
title_full_unstemmed Photochromic relaxation kinetics
title_sort photochromic relaxation kinetics
url http://hdl.handle.net/20.500.12110/paper_15421406_v430_n_p281_Jovin
work_keys_str_mv AT jovintm photochromicrelaxationkinetics
AT jareserijmanea photochromicrelaxationkinetics
_version_ 1782024606598561792

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