Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes

Advanced oxidation technologies (AOT) were applied for the production of accurately controlled oxidized multi-walled carbon nanotubes. Fenton process is effective to get carboxylic (-COO - or -COOH) and OH groups on the surface of carbon nanotubes while Photofenton and UV/H 2O 2 processes mostly pro...

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Autores principales: Escobar, M., Goyanes, S., Corcuera, M.A., Eceiza, A., Mondragon, I., Rubiolo, G.H., Candal, R.J.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15334880_v9_n10_p6228_Escobar
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spelling todo:paper_15334880_v9_n10_p6228_Escobar2023-10-03T16:21:34Z Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes Escobar, M. Goyanes, S. Corcuera, M.A. Eceiza, A. Mondragon, I. Rubiolo, G.H. Candal, R.J. Carbon nanotubes Controlled oxidation Fenton Photo-fenton Acid treatments Advanced Oxidation Processes Advanced oxidation technology Chemical techniques Controlled oxidation COOH group Fenton Fenton process Field emission scanning electron microscopy Functionalizations OH group Photo-fenton Carbon nanotubes Field emission Field emission microscopes Fourier transform infrared spectroscopy Oxidation Scanning electron microscopy Spectroscopic analysis Spectroscopy Transmission electron microscopy Wastewater treatment Multiwalled carbon nanotubes (MWCN) Advanced oxidation technologies (AOT) were applied for the production of accurately controlled oxidized multi-walled carbon nanotubes. Fenton process is effective to get carboxylic (-COO - or -COOH) and OH groups on the surface of carbon nanotubes while Photofenton and UV/H 2O 2 processes mostly produce OH groups on surface of multiwalled carbon nanotubes (MWCNT). All of them preserve the structure of MWCNT allowing to achieve accurately controlled oxidized MWCNT. Fourier transform infrared spectroscopy (FTIR) and thermogravimetical analysis (TGA) show that the acid treatment is the more efficient technique to generate COOH groups on MWCNT surface. However, this chemical technique generates strong damages on the MWCNT structure, as demonstrated by TGA, field emission scanning electron microscopy and transmission electron microscopy results. Copyright © 2009 American Scientific Publishers. Fil:Escobar, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Candal, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15334880_v9_n10_p6228_Escobar
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Carbon nanotubes
Controlled oxidation
Fenton
Photo-fenton
Acid treatments
Advanced Oxidation Processes
Advanced oxidation technology
Chemical techniques
Controlled oxidation
COOH group
Fenton
Fenton process
Field emission scanning electron microscopy
Functionalizations
OH group
Photo-fenton
Carbon nanotubes
Field emission
Field emission microscopes
Fourier transform infrared spectroscopy
Oxidation
Scanning electron microscopy
Spectroscopic analysis
Spectroscopy
Transmission electron microscopy
Wastewater treatment
Multiwalled carbon nanotubes (MWCN)
spellingShingle Carbon nanotubes
Controlled oxidation
Fenton
Photo-fenton
Acid treatments
Advanced Oxidation Processes
Advanced oxidation technology
Chemical techniques
Controlled oxidation
COOH group
Fenton
Fenton process
Field emission scanning electron microscopy
Functionalizations
OH group
Photo-fenton
Carbon nanotubes
Field emission
Field emission microscopes
Fourier transform infrared spectroscopy
Oxidation
Scanning electron microscopy
Spectroscopic analysis
Spectroscopy
Transmission electron microscopy
Wastewater treatment
Multiwalled carbon nanotubes (MWCN)
Escobar, M.
Goyanes, S.
Corcuera, M.A.
Eceiza, A.
Mondragon, I.
Rubiolo, G.H.
Candal, R.J.
Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
topic_facet Carbon nanotubes
Controlled oxidation
Fenton
Photo-fenton
Acid treatments
Advanced Oxidation Processes
Advanced oxidation technology
Chemical techniques
Controlled oxidation
COOH group
Fenton
Fenton process
Field emission scanning electron microscopy
Functionalizations
OH group
Photo-fenton
Carbon nanotubes
Field emission
Field emission microscopes
Fourier transform infrared spectroscopy
Oxidation
Scanning electron microscopy
Spectroscopic analysis
Spectroscopy
Transmission electron microscopy
Wastewater treatment
Multiwalled carbon nanotubes (MWCN)
description Advanced oxidation technologies (AOT) were applied for the production of accurately controlled oxidized multi-walled carbon nanotubes. Fenton process is effective to get carboxylic (-COO - or -COOH) and OH groups on the surface of carbon nanotubes while Photofenton and UV/H 2O 2 processes mostly produce OH groups on surface of multiwalled carbon nanotubes (MWCNT). All of them preserve the structure of MWCNT allowing to achieve accurately controlled oxidized MWCNT. Fourier transform infrared spectroscopy (FTIR) and thermogravimetical analysis (TGA) show that the acid treatment is the more efficient technique to generate COOH groups on MWCNT surface. However, this chemical technique generates strong damages on the MWCNT structure, as demonstrated by TGA, field emission scanning electron microscopy and transmission electron microscopy results. Copyright © 2009 American Scientific Publishers.
format JOUR
author Escobar, M.
Goyanes, S.
Corcuera, M.A.
Eceiza, A.
Mondragon, I.
Rubiolo, G.H.
Candal, R.J.
author_facet Escobar, M.
Goyanes, S.
Corcuera, M.A.
Eceiza, A.
Mondragon, I.
Rubiolo, G.H.
Candal, R.J.
author_sort Escobar, M.
title Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
title_short Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
title_full Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
title_fullStr Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
title_full_unstemmed Purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
title_sort purification and functionalization of carbon nanotubes by classical and advanced oxidation processes
url http://hdl.handle.net/20.500.12110/paper_15334880_v9_n10_p6228_Escobar
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