Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a...
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todo:paper_15306984_v12_n7_p3537_Diaz2023-10-03T16:21:18Z Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard Díaz, S.A. Giordano, L. Jovin, T.M. Jares-Erijman, E.A. FRET internal standard photochromism Quantum dots ratiometric imaging Background signals Dual emissions Fluorescence intensity ratio FRET Internal standards Organic fluorophores Photo-switchable QD emissions Ratiometric Ratiometric imaging Semiconductor nanoparticles Organic polymers Photochromism Semiconductor quantum dots Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a diheteroarylethene photochromic FRET acceptor as well as a spectrally distinct organic fluorophore, photoswitchable QDs were prepared that are small, biocompatible, and feature ratiometric dual emission. With programmed irradiation, the fluorescence intensity ratio can be modified by up to ∼100%. © 2012 American Chemical Society. Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15306984_v12_n7_p3537_Diaz |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
FRET internal standard photochromism Quantum dots ratiometric imaging Background signals Dual emissions Fluorescence intensity ratio FRET Internal standards Organic fluorophores Photo-switchable QD emissions Ratiometric Ratiometric imaging Semiconductor nanoparticles Organic polymers Photochromism Semiconductor quantum dots |
spellingShingle |
FRET internal standard photochromism Quantum dots ratiometric imaging Background signals Dual emissions Fluorescence intensity ratio FRET Internal standards Organic fluorophores Photo-switchable QD emissions Ratiometric Ratiometric imaging Semiconductor nanoparticles Organic polymers Photochromism Semiconductor quantum dots Díaz, S.A. Giordano, L. Jovin, T.M. Jares-Erijman, E.A. Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
topic_facet |
FRET internal standard photochromism Quantum dots ratiometric imaging Background signals Dual emissions Fluorescence intensity ratio FRET Internal standards Organic fluorophores Photo-switchable QD emissions Ratiometric Ratiometric imaging Semiconductor nanoparticles Organic polymers Photochromism Semiconductor quantum dots |
description |
Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a diheteroarylethene photochromic FRET acceptor as well as a spectrally distinct organic fluorophore, photoswitchable QDs were prepared that are small, biocompatible, and feature ratiometric dual emission. With programmed irradiation, the fluorescence intensity ratio can be modified by up to ∼100%. © 2012 American Chemical Society. |
format |
JOUR |
author |
Díaz, S.A. Giordano, L. Jovin, T.M. Jares-Erijman, E.A. |
author_facet |
Díaz, S.A. Giordano, L. Jovin, T.M. Jares-Erijman, E.A. |
author_sort |
Díaz, S.A. |
title |
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
title_short |
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
title_full |
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
title_fullStr |
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
title_full_unstemmed |
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard |
title_sort |
modulation of a photoswitchable dual-color quantum dot containing a photochromic fret acceptor and an internal standard |
url |
http://hdl.handle.net/20.500.12110/paper_15306984_v12_n7_p3537_Diaz |
work_keys_str_mv |
AT diazsa modulationofaphotoswitchabledualcolorquantumdotcontainingaphotochromicfretacceptorandaninternalstandard AT giordanol modulationofaphotoswitchabledualcolorquantumdotcontainingaphotochromicfretacceptorandaninternalstandard AT jovintm modulationofaphotoswitchabledualcolorquantumdotcontainingaphotochromicfretacceptorandaninternalstandard AT jareserijmanea modulationofaphotoswitchabledualcolorquantumdotcontainingaphotochromicfretacceptorandaninternalstandard |
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1782026565269323776 |