Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard

Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a...

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Autores principales: Díaz, S.A., Giordano, L., Jovin, T.M., Jares-Erijman, E.A.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15306984_v12_n7_p3537_Diaz
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spelling todo:paper_15306984_v12_n7_p3537_Diaz2023-10-03T16:21:18Z Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard Díaz, S.A. Giordano, L. Jovin, T.M. Jares-Erijman, E.A. FRET internal standard photochromism Quantum dots ratiometric imaging Background signals Dual emissions Fluorescence intensity ratio FRET Internal standards Organic fluorophores Photo-switchable QD emissions Ratiometric Ratiometric imaging Semiconductor nanoparticles Organic polymers Photochromism Semiconductor quantum dots Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a diheteroarylethene photochromic FRET acceptor as well as a spectrally distinct organic fluorophore, photoswitchable QDs were prepared that are small, biocompatible, and feature ratiometric dual emission. With programmed irradiation, the fluorescence intensity ratio can be modified by up to ∼100%. © 2012 American Chemical Society. Fil:Giordano, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15306984_v12_n7_p3537_Diaz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic FRET
internal standard
photochromism
Quantum dots
ratiometric imaging
Background signals
Dual emissions
Fluorescence intensity ratio
FRET
Internal standards
Organic fluorophores
Photo-switchable
QD emissions
Ratiometric
Ratiometric imaging
Semiconductor nanoparticles
Organic polymers
Photochromism
Semiconductor quantum dots
spellingShingle FRET
internal standard
photochromism
Quantum dots
ratiometric imaging
Background signals
Dual emissions
Fluorescence intensity ratio
FRET
Internal standards
Organic fluorophores
Photo-switchable
QD emissions
Ratiometric
Ratiometric imaging
Semiconductor nanoparticles
Organic polymers
Photochromism
Semiconductor quantum dots
Díaz, S.A.
Giordano, L.
Jovin, T.M.
Jares-Erijman, E.A.
Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
topic_facet FRET
internal standard
photochromism
Quantum dots
ratiometric imaging
Background signals
Dual emissions
Fluorescence intensity ratio
FRET
Internal standards
Organic fluorophores
Photo-switchable
QD emissions
Ratiometric
Ratiometric imaging
Semiconductor nanoparticles
Organic polymers
Photochromism
Semiconductor quantum dots
description Photoswitchable semiconductor nanoparticles, quantum dots (QDs), couple the advantages of conventional QDs with the ability to reversibly modulate the QD emission, thereby improving signal detection by rejection of background signals. Using a simple coating methodology with polymers incorporating a diheteroarylethene photochromic FRET acceptor as well as a spectrally distinct organic fluorophore, photoswitchable QDs were prepared that are small, biocompatible, and feature ratiometric dual emission. With programmed irradiation, the fluorescence intensity ratio can be modified by up to ∼100%. © 2012 American Chemical Society.
format JOUR
author Díaz, S.A.
Giordano, L.
Jovin, T.M.
Jares-Erijman, E.A.
author_facet Díaz, S.A.
Giordano, L.
Jovin, T.M.
Jares-Erijman, E.A.
author_sort Díaz, S.A.
title Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
title_short Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
title_full Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
title_fullStr Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
title_full_unstemmed Modulation of a photoswitchable dual-color quantum dot containing a photochromic FRET acceptor and an internal standard
title_sort modulation of a photoswitchable dual-color quantum dot containing a photochromic fret acceptor and an internal standard
url http://hdl.handle.net/20.500.12110/paper_15306984_v12_n7_p3537_Diaz
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