Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity

One of the main constraints for the implementation of hydrogen as energy carrier is the lack of an efficient and safe hydrogen storage system. Hydrogen storage in solid state through hydride compounds formation is a potential alternative to address this problem. In this work, it is studied the effec...

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Autores principales: Martinelli, H., Riglos, V.C., Puszkiel, J.
Formato: JOUR
Materias:
Hydrogen
Kinetics
Reactive hydride composites
Titanates
Titanium dioxide
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15177076_v23_n2_p_Martinelli
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_15177076_v23_n2_p_Martinelli2023-10-03T16:19:52Z Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity Martinelli, H. Riglos, V.C. Puszkiel, J. Hydrogen Kinetics Reactive hydride composites Titanates Titanium dioxide One of the main constraints for the implementation of hydrogen as energy carrier is the lack of an efficient and safe hydrogen storage system. Hydrogen storage in solid state through hydride compounds formation is a potential alternative to address this problem. In this work, it is studied the effect of different titanium based compounds (TiB2, LixTiO2) on the kinetic behavior of 2LiBH4+MgH2 reactive hydride composite. It is found that nanometric particles of titanates (LixTiO2) noticeably improve the first non-isothermal dehydrogenation behavior of the2LiBH4+MgH2, reducing the complete H2 release time from 35 h to 2 h. Moreover, the LixTiO2 addition improves the isothermal hydrogenation/dehydrogenation kinetic behavior. The information gained by advanced techniques such as transmission electron microscopy and Raman spectroscopy, among others, help us to elucidate that the addition of LixTiO2 to2LiBH4+MgH2 allows the hydrogen uptake/release via a novel and reversible mechanism. © 2018, Universidade Federal do Rio de Janeiro. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15177076_v23_n2_p_Martinelli
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Hydrogen
Kinetics
Reactive hydride composites
Titanates
Titanium dioxide
spellingShingle Hydrogen
Kinetics
Reactive hydride composites
Titanates
Titanium dioxide
Martinelli, H.
Riglos, V.C.
Puszkiel, J.
Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
topic_facet Hydrogen
Kinetics
Reactive hydride composites
Titanates
Titanium dioxide
description One of the main constraints for the implementation of hydrogen as energy carrier is the lack of an efficient and safe hydrogen storage system. Hydrogen storage in solid state through hydride compounds formation is a potential alternative to address this problem. In this work, it is studied the effect of different titanium based compounds (TiB2, LixTiO2) on the kinetic behavior of 2LiBH4+MgH2 reactive hydride composite. It is found that nanometric particles of titanates (LixTiO2) noticeably improve the first non-isothermal dehydrogenation behavior of the2LiBH4+MgH2, reducing the complete H2 release time from 35 h to 2 h. Moreover, the LixTiO2 addition improves the isothermal hydrogenation/dehydrogenation kinetic behavior. The information gained by advanced techniques such as transmission electron microscopy and Raman spectroscopy, among others, help us to elucidate that the addition of LixTiO2 to2LiBH4+MgH2 allows the hydrogen uptake/release via a novel and reversible mechanism. © 2018, Universidade Federal do Rio de Janeiro. All rights reserved.
format JOUR
author Martinelli, H.
Riglos, V.C.
Puszkiel, J.
author_facet Martinelli, H.
Riglos, V.C.
Puszkiel, J.
author_sort Martinelli, H.
title Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
title_short Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
title_full Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
title_fullStr Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
title_full_unstemmed Study and characterization of the effect of titanium-based compounds on the hydride system Li-B-Mg-H with high hydrogen storage capacity
title_sort study and characterization of the effect of titanium-based compounds on the hydride system li-b-mg-h with high hydrogen storage capacity
url http://hdl.handle.net/20.500.12110/paper_15177076_v23_n2_p_Martinelli
work_keys_str_mv AT martinellih studyandcharacterizationoftheeffectoftitaniumbasedcompoundsonthehydridesystemlibmghwithhighhydrogenstoragecapacity
AT riglosvc studyandcharacterizationoftheeffectoftitaniumbasedcompoundsonthehydridesystemlibmghwithhighhydrogenstoragecapacity
AT puszkielj studyandcharacterizationoftheeffectoftitaniumbasedcompoundsonthehydridesystemlibmghwithhighhydrogenstoragecapacity
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