Biaryl formation involving carbon-based leaving groups: Why not?
(Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-bas...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi |
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todo:paper_14337851_v47_n52_p10022_Bonesi2023-10-03T16:14:11Z Biaryl formation involving carbon-based leaving groups: Why not? Bonesi, S.M. Fagnoni, M. Albini, A. Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations (Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-based leaving group has decisive advantages. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations |
| spellingShingle |
Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations Bonesi, S.M. Fagnoni, M. Albini, A. Biaryl formation involving carbon-based leaving groups: Why not? |
| topic_facet |
Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations |
| description |
(Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-based leaving group has decisive advantages. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. |
| format |
JOUR |
| author |
Bonesi, S.M. Fagnoni, M. Albini, A. |
| author_facet |
Bonesi, S.M. Fagnoni, M. Albini, A. |
| author_sort |
Bonesi, S.M. |
| title |
Biaryl formation involving carbon-based leaving groups: Why not? |
| title_short |
Biaryl formation involving carbon-based leaving groups: Why not? |
| title_full |
Biaryl formation involving carbon-based leaving groups: Why not? |
| title_fullStr |
Biaryl formation involving carbon-based leaving groups: Why not? |
| title_full_unstemmed |
Biaryl formation involving carbon-based leaving groups: Why not? |
| title_sort |
biaryl formation involving carbon-based leaving groups: why not? |
| url |
http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi |
| work_keys_str_mv |
AT bonesism biarylformationinvolvingcarbonbasedleavinggroupswhynot AT fagnonim biarylformationinvolvingcarbonbasedleavinggroupswhynot AT albinia biarylformationinvolvingcarbonbasedleavinggroupswhynot |
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1807321494053715968 |