Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10...
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todo:paper_13882481_v8_n1_p179_Volker2023-10-03T16:12:38Z Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel Völker, E. Inchauspe, C.G. Calvo, E.J. Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved. Fil:Völker, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions |
spellingShingle |
Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions Völker, E. Inchauspe, C.G. Calvo, E.J. Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
topic_facet |
Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions |
description |
Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved. |
format |
JOUR |
author |
Völker, E. Inchauspe, C.G. Calvo, E.J. |
author_facet |
Völker, E. Inchauspe, C.G. Calvo, E.J. |
author_sort |
Völker, E. |
title |
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
title_short |
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
title_full |
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
title_fullStr |
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
title_full_unstemmed |
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
title_sort |
scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel |
url |
http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker |
work_keys_str_mv |
AT volkere scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel AT inchauspecg scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel AT calvoej scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel |
_version_ |
1807322063437824000 |