Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel

Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10...

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Autores principales: Völker, E., Inchauspe, C.G., Calvo, E.J.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
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spelling todo:paper_13882481_v8_n1_p179_Volker2023-10-03T16:12:38Z Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel Völker, E. Inchauspe, C.G. Calvo, E.J. Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved. Fil:Völker, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
spellingShingle Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
Völker, E.
Inchauspe, C.G.
Calvo, E.J.
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
topic_facet Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
description Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved.
format JOUR
author Völker, E.
Inchauspe, C.G.
Calvo, E.J.
author_facet Völker, E.
Inchauspe, C.G.
Calvo, E.J.
author_sort Völker, E.
title Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_short Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_full Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_fullStr Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_full_unstemmed Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_sort scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
url http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
work_keys_str_mv AT volkere scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel
AT inchauspecg scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel
AT calvoej scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel
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