Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution

DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution...

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Detalles Bibliográficos
Autores principales: Mozhzhukhina, N., Marchini, F., Torres, W.R., Tesio, A.Y., Mendez De Leo, L.P., Williams, F.J., Calvo, E.J.
Formato: JOUR
Materias:
Air
Battery
CO2
DMSO
Lithium
Oxygen
Carbon
Carbon dioxide
Dimethyl sulfoxide
Electric batteries
Electrolytes
Electrolytic reduction
Organic solvents
Carbon dioxide evolution
Li-air batteries
Oxygen evolution reaction
Oxygen reduction reaction
Research communities
Solvent decompositions
Lithium batteries
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_13882481_v80_n_p16_Mozhzhukhina
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_13882481_v80_n_p16_Mozhzhukhina
record_format dspace
spelling todo:paper_13882481_v80_n_p16_Mozhzhukhina2023-10-03T16:12:38Z Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution Mozhzhukhina, N. Marchini, F. Torres, W.R. Tesio, A.Y. Mendez De Leo, L.P. Williams, F.J. Calvo, E.J. Air Battery CO2 DMSO Lithium Oxygen Air Carbon Carbon dioxide Dimethyl sulfoxide Electric batteries Electrolytes Electrolytic reduction Lithium Organic solvents Oxygen Battery Carbon dioxide evolution DMSO Li-air batteries Oxygen evolution reaction Oxygen reduction reaction Research communities Solvent decompositions Lithium batteries DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition. © 2017 Elsevier B.V. Fil:Mendez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Williams, F.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v80_n_p16_Mozhzhukhina
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Air
Battery
CO2
DMSO
Lithium
Oxygen
Air
Carbon
Carbon dioxide
Dimethyl sulfoxide
Electric batteries
Electrolytes
Electrolytic reduction
Lithium
Organic solvents
Oxygen
Battery
Carbon dioxide evolution
DMSO
Li-air batteries
Oxygen evolution reaction
Oxygen reduction reaction
Research communities
Solvent decompositions
Lithium batteries
spellingShingle Air
Battery
CO2
DMSO
Lithium
Oxygen
Air
Carbon
Carbon dioxide
Dimethyl sulfoxide
Electric batteries
Electrolytes
Electrolytic reduction
Lithium
Organic solvents
Oxygen
Battery
Carbon dioxide evolution
DMSO
Li-air batteries
Oxygen evolution reaction
Oxygen reduction reaction
Research communities
Solvent decompositions
Lithium batteries
Mozhzhukhina, N.
Marchini, F.
Torres, W.R.
Tesio, A.Y.
Mendez De Leo, L.P.
Williams, F.J.
Calvo, E.J.
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
topic_facet Air
Battery
CO2
DMSO
Lithium
Oxygen
Air
Carbon
Carbon dioxide
Dimethyl sulfoxide
Electric batteries
Electrolytes
Electrolytic reduction
Lithium
Organic solvents
Oxygen
Battery
Carbon dioxide evolution
DMSO
Li-air batteries
Oxygen evolution reaction
Oxygen reduction reaction
Research communities
Solvent decompositions
Lithium batteries
description DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition. © 2017 Elsevier B.V.
format JOUR
author Mozhzhukhina, N.
Marchini, F.
Torres, W.R.
Tesio, A.Y.
Mendez De Leo, L.P.
Williams, F.J.
Calvo, E.J.
author_facet Mozhzhukhina, N.
Marchini, F.
Torres, W.R.
Tesio, A.Y.
Mendez De Leo, L.P.
Williams, F.J.
Calvo, E.J.
author_sort Mozhzhukhina, N.
title Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
title_short Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
title_full Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
title_fullStr Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
title_full_unstemmed Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
title_sort insights into dimethyl sulfoxide decomposition in li-o2 battery: understanding carbon dioxide evolution
url http://hdl.handle.net/20.500.12110/paper_13882481_v80_n_p16_Mozhzhukhina
work_keys_str_mv AT mozhzhukhinan insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT marchinif insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT torreswr insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT tesioay insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT mendezdeleolp insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT williamsfj insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
AT calvoej insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution
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