Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy
A new method for measuring local interfacial impedance properties with high lateral resolution was developed by combination of electrochemical impedance spectroscopy (EIS) with scanning electrochemical microscopy (SECM). Alternating current scanning electrochemical microscopy (AC-SECM) allowed to id...
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todo:paper_13882481_v4_n2_p134_BallesterosKatemann2023-10-03T16:12:38Z Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy Ballesteros Katemann, B. Schulte, A. Calvo, E.J. Koudelka-Hep, M. Schuhmann, W. Electrochemical impedance spectroscopy Microelectrode Scanning electrochemical microscopy,SECM electrolyte platinum alternating current article electric conductivity electrochemical impedance spectroscopy electrochemistry impedance liquid microelectrode optical resolution oxidation reduction reaction scanning electrochemical microscopy scanning electron microscopy solid spectroscopy surface property A new method for measuring local interfacial impedance properties with high lateral resolution was developed by combination of electrochemical impedance spectroscopy (EIS) with scanning electrochemical microscopy (SECM). Alternating current scanning electrochemical microscopy (AC-SECM) allowed to identify and visualise microscopic domains of different conductivity/electrochemical activities on solid/liquid interfaces immersed into an electrolyte. The performance of the method was illustrated by imaging an array of Pt-band microelectrodes in solutions of low conductivity in the absence of any redox mediator. © 2002 Elsevier Science B.V. All rights reserved. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v4_n2_p134_BallesterosKatemann |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Electrochemical impedance spectroscopy Microelectrode Scanning electrochemical microscopy,SECM electrolyte platinum alternating current article electric conductivity electrochemical impedance spectroscopy electrochemistry impedance liquid microelectrode optical resolution oxidation reduction reaction scanning electrochemical microscopy scanning electron microscopy solid spectroscopy surface property |
| spellingShingle |
Electrochemical impedance spectroscopy Microelectrode Scanning electrochemical microscopy,SECM electrolyte platinum alternating current article electric conductivity electrochemical impedance spectroscopy electrochemistry impedance liquid microelectrode optical resolution oxidation reduction reaction scanning electrochemical microscopy scanning electron microscopy solid spectroscopy surface property Ballesteros Katemann, B. Schulte, A. Calvo, E.J. Koudelka-Hep, M. Schuhmann, W. Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| topic_facet |
Electrochemical impedance spectroscopy Microelectrode Scanning electrochemical microscopy,SECM electrolyte platinum alternating current article electric conductivity electrochemical impedance spectroscopy electrochemistry impedance liquid microelectrode optical resolution oxidation reduction reaction scanning electrochemical microscopy scanning electron microscopy solid spectroscopy surface property |
| description |
A new method for measuring local interfacial impedance properties with high lateral resolution was developed by combination of electrochemical impedance spectroscopy (EIS) with scanning electrochemical microscopy (SECM). Alternating current scanning electrochemical microscopy (AC-SECM) allowed to identify and visualise microscopic domains of different conductivity/electrochemical activities on solid/liquid interfaces immersed into an electrolyte. The performance of the method was illustrated by imaging an array of Pt-band microelectrodes in solutions of low conductivity in the absence of any redox mediator. © 2002 Elsevier Science B.V. All rights reserved. |
| format |
JOUR |
| author |
Ballesteros Katemann, B. Schulte, A. Calvo, E.J. Koudelka-Hep, M. Schuhmann, W. |
| author_facet |
Ballesteros Katemann, B. Schulte, A. Calvo, E.J. Koudelka-Hep, M. Schuhmann, W. |
| author_sort |
Ballesteros Katemann, B. |
| title |
Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| title_short |
Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| title_full |
Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| title_fullStr |
Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| title_full_unstemmed |
Localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| title_sort |
localised electrochemical impedance spectroscopy with high lateral resolution by means of alternating current scanning electrochemical microscopy |
| url |
http://hdl.handle.net/20.500.12110/paper_13882481_v4_n2_p134_BallesterosKatemann |
| work_keys_str_mv |
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