Deacetylation of furanosides using banana as biocatalyst
The deacylation under hydrolytic conditions of methyl 2,3,5-tri-O-acetyl-α-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-β-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-α,β-d-arabinofuranosides and alkyl 2,3,5-tri-O-acetyl-α,β-xylofuranosides have been studied using banana whole tissue as biocatalyst. R...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_13811177_v44_n3-4_p138_TavernaPorro |
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todo:paper_13811177_v44_n3-4_p138_TavernaPorro2023-10-03T16:11:45Z Deacetylation of furanosides using banana as biocatalyst Taverna-Porro, M. Iglesias, L.E. Montserrat, J.M. Iribarren, A.M. Banana Deprotection Furanosides Hydrolases Regioselective deacetylation Hydrolases Regioselective deacetylation Biocatalysts Fruits Hydrolysis Tissue Carbohydrates arabinoside furan derivative hydrolase methyl 2,3 di o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl beta dextro ribofuranoside ribose unclassified drug article banana biocatalyst chemical structure deacetylation deprotection reaction enzyme mechanism enzyme substrate hydrolysis quantitative analysis reaction analysis Carbohydrates Deacetylation Fruits Furanosides Hydrolysis Tissue The deacylation under hydrolytic conditions of methyl 2,3,5-tri-O-acetyl-α-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-β-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-α,β-d-arabinofuranosides and alkyl 2,3,5-tri-O-acetyl-α,β-xylofuranosides have been studied using banana whole tissue as biocatalyst. Reaction regioselectivity strongly depends on substrate structure. Hydrolysis of methyl 2,3,5-tri-O-acetyl-α-d-ribofuranoside afforded methyl 2,3-di-O-acetyl-α-d-ribofuranoside in quantitative yield. © 2006 Elsevier B.V. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13811177_v44_n3-4_p138_TavernaPorro |
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Universidad de Buenos Aires |
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I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Banana Deprotection Furanosides Hydrolases Regioselective deacetylation Hydrolases Regioselective deacetylation Biocatalysts Fruits Hydrolysis Tissue Carbohydrates arabinoside furan derivative hydrolase methyl 2,3 di o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl beta dextro ribofuranoside ribose unclassified drug article banana biocatalyst chemical structure deacetylation deprotection reaction enzyme mechanism enzyme substrate hydrolysis quantitative analysis reaction analysis Carbohydrates Deacetylation Fruits Furanosides Hydrolysis Tissue |
| spellingShingle |
Banana Deprotection Furanosides Hydrolases Regioselective deacetylation Hydrolases Regioselective deacetylation Biocatalysts Fruits Hydrolysis Tissue Carbohydrates arabinoside furan derivative hydrolase methyl 2,3 di o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl beta dextro ribofuranoside ribose unclassified drug article banana biocatalyst chemical structure deacetylation deprotection reaction enzyme mechanism enzyme substrate hydrolysis quantitative analysis reaction analysis Carbohydrates Deacetylation Fruits Furanosides Hydrolysis Tissue Taverna-Porro, M. Iglesias, L.E. Montserrat, J.M. Iribarren, A.M. Deacetylation of furanosides using banana as biocatalyst |
| topic_facet |
Banana Deprotection Furanosides Hydrolases Regioselective deacetylation Hydrolases Regioselective deacetylation Biocatalysts Fruits Hydrolysis Tissue Carbohydrates arabinoside furan derivative hydrolase methyl 2,3 di o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl alpha dextro ribofuranoside methyl 2,3,5 tri o acetyl beta dextro ribofuranoside ribose unclassified drug article banana biocatalyst chemical structure deacetylation deprotection reaction enzyme mechanism enzyme substrate hydrolysis quantitative analysis reaction analysis Carbohydrates Deacetylation Fruits Furanosides Hydrolysis Tissue |
| description |
The deacylation under hydrolytic conditions of methyl 2,3,5-tri-O-acetyl-α-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-β-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-α,β-d-arabinofuranosides and alkyl 2,3,5-tri-O-acetyl-α,β-xylofuranosides have been studied using banana whole tissue as biocatalyst. Reaction regioselectivity strongly depends on substrate structure. Hydrolysis of methyl 2,3,5-tri-O-acetyl-α-d-ribofuranoside afforded methyl 2,3-di-O-acetyl-α-d-ribofuranoside in quantitative yield. © 2006 Elsevier B.V. All rights reserved. |
| format |
JOUR |
| author |
Taverna-Porro, M. Iglesias, L.E. Montserrat, J.M. Iribarren, A.M. |
| author_facet |
Taverna-Porro, M. Iglesias, L.E. Montserrat, J.M. Iribarren, A.M. |
| author_sort |
Taverna-Porro, M. |
| title |
Deacetylation of furanosides using banana as biocatalyst |
| title_short |
Deacetylation of furanosides using banana as biocatalyst |
| title_full |
Deacetylation of furanosides using banana as biocatalyst |
| title_fullStr |
Deacetylation of furanosides using banana as biocatalyst |
| title_full_unstemmed |
Deacetylation of furanosides using banana as biocatalyst |
| title_sort |
deacetylation of furanosides using banana as biocatalyst |
| url |
http://hdl.handle.net/20.500.12110/paper_13811177_v44_n3-4_p138_TavernaPorro |
| work_keys_str_mv |
AT tavernaporrom deacetylationoffuranosidesusingbananaasbiocatalyst AT iglesiasle deacetylationoffuranosidesusingbananaasbiocatalyst AT montserratjm deacetylationoffuranosidesusingbananaasbiocatalyst AT iribarrenam deacetylationoffuranosidesusingbananaasbiocatalyst |
| _version_ |
1782023702237413376 |