Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion

Most of the systems possessing true two-electron three-center interactions are electron deficient compounds like boron hydrids, closo-boranes, and some organic ions such as butonium cations. In this work, we perform a detailed study of the electron distribution for two different types of systems to...

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Autores principales: Lobayan, R.M., Bochicchio, R.C.
Formato: JOUR
Materias:
Beryllium
Magnesium
Organometallics
Topology
Earth alkaline
Electron distributions
Electron-deficient compounds
Gaseous phase
Metallic ions
Organic ions
Systems possessing
Topological analysis
Electrons
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_10895639_v119_n27_p7000_Lobayan
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_10895639_v119_n27_p7000_Lobayan
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spelling todo:paper_10895639_v119_n27_p7000_Lobayan2023-10-03T16:04:50Z Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion Lobayan, R.M. Bochicchio, R.C. Beryllium Magnesium Organometallics Topology Earth alkaline Electron distributions Electron-deficient compounds Gaseous phase Metallic ions Organic ions Systems possessing Topological analysis Electrons Most of the systems possessing true two-electron three-center interactions are electron deficient compounds like boron hydrids, closo-boranes, and some organic ions such as butonium cations. In this work, we perform a detailed study of the electron distribution for two different types of systems to which likewise interactions has been adjudicated: organometallic CH<inf>4</inf>-Me+p (p = 1, 2) adducts with Me, alkaline and earth alkaline metallic ions of Li, Na, K, Be, Mg, Ca in their stable gaseous phase and X<inf>4</inf>H+ (X = P, As) simple clusters. For this purpose, topological analysis of the electron density decomposed into its effectively paired and unpaired contributions has been carried out looking for complex interactions. © 2015 American Chemical Society. Fil:Bochicchio, R.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_10895639_v119_n27_p7000_Lobayan
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Beryllium
Magnesium
Organometallics
Topology
Earth alkaline
Electron distributions
Electron-deficient compounds
Gaseous phase
Metallic ions
Organic ions
Systems possessing
Topological analysis
Electrons
spellingShingle Beryllium
Magnesium
Organometallics
Topology
Earth alkaline
Electron distributions
Electron-deficient compounds
Gaseous phase
Metallic ions
Organic ions
Systems possessing
Topological analysis
Electrons
Lobayan, R.M.
Bochicchio, R.C.
Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
topic_facet Beryllium
Magnesium
Organometallics
Topology
Earth alkaline
Electron distributions
Electron-deficient compounds
Gaseous phase
Metallic ions
Organic ions
Systems possessing
Topological analysis
Electrons
description Most of the systems possessing true two-electron three-center interactions are electron deficient compounds like boron hydrids, closo-boranes, and some organic ions such as butonium cations. In this work, we perform a detailed study of the electron distribution for two different types of systems to which likewise interactions has been adjudicated: organometallic CH<inf>4</inf>-Me+p (p = 1, 2) adducts with Me, alkaline and earth alkaline metallic ions of Li, Na, K, Be, Mg, Ca in their stable gaseous phase and X<inf>4</inf>H+ (X = P, As) simple clusters. For this purpose, topological analysis of the electron density decomposed into its effectively paired and unpaired contributions has been carried out looking for complex interactions. © 2015 American Chemical Society.
format JOUR
author Lobayan, R.M.
Bochicchio, R.C.
author_facet Lobayan, R.M.
Bochicchio, R.C.
author_sort Lobayan, R.M.
title Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
title_short Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
title_full Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
title_fullStr Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
title_full_unstemmed Do Organometallic CH<inf>4</inf>-Me+p Adducts and X<inf>4</inf>H+ (X = P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
title_sort do organometallic ch<inf>4</inf>-me+p adducts and x<inf>4</inf>h+ (x = p, as) clusters undergo two-electron three-center interactions? some aspects of discussion
url http://hdl.handle.net/20.500.12110/paper_10895639_v119_n27_p7000_Lobayan
work_keys_str_mv AT lobayanrm doorganometallicchinf4infmepadductsandxinf4infhxpasclustersundergotwoelectronthreecenterinteractionssomeaspectsofdiscussion
AT bochicchiorc doorganometallicchinf4infmepadductsandxinf4infhxpasclustersundergotwoelectronthreecenterinteractionssomeaspectsofdiscussion
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