In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry

The probe electrospray ionization (PESI) is an ESI-based ionization technique that generates electrospray from the tip of a solid metal needle. In the present work, we describe the PESI mass spectra obtained by in situ measurement of soybeans and several nuts (peanuts, walnuts, cashew nuts, macadami...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Petroselli, G., Mandal, M.K., Chen, L.C., Hiraoka, K., Nonami, H., Erra-Balsells, R.
Formato:	JOUR
Materias:	almonds cashew nuts ESI-MS macadamia nuts peanuts PESI pistachios rancidification walnuts Electrospray ionization Glycerol Ionization Mass spectrometers Mass spectrometry Needles Phospholipids Probes Cashew nut Macadamia nuts Principal component analysis hydroperoxide methanol phospholipid triacylglycerol acidification aging air almond Article cashew nut comparative study electrospray mass spectrometry lipid analysis lipid composition Macadamia molecular probe molecular weight nut oxidation peanut principal component analysis priority journal probe electrospray ionization mass spectrometry soybean sunlight walnut Arachis chemistry devices procedures Anacardium occidentale Glycine max Juglans Nuts Principal Component Analysis Soybeans Spectrometry, Mass, Electrospray Ionization Triglycerides
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_10765174_v50_n4_p676_Petroselli
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_10765174_v50_n4_p676_Petroselli
record_format	dspace
spelling	todo:paper_10765174_v50_n4_p676_Petroselli2023-10-03T16:03:26Z In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry Petroselli, G. Mandal, M.K. Chen, L.C. Hiraoka, K. Nonami, H. Erra-Balsells, R. almonds cashew nuts ESI-MS macadamia nuts peanuts PESI pistachios rancidification walnuts Electrospray ionization Glycerol Ionization Mass spectrometers Mass spectrometry Needles Phospholipids Probes almonds Cashew nut ESI-MS Macadamia nuts peanuts PESI pistachios rancidification walnuts Principal component analysis hydroperoxide methanol phospholipid triacylglycerol phospholipid triacylglycerol acidification aging air almond Article cashew nut comparative study electrospray mass spectrometry lipid analysis lipid composition Macadamia molecular probe molecular weight nut oxidation peanut principal component analysis priority journal probe electrospray ionization mass spectrometry rancidification soybean sunlight walnut Arachis chemistry devices electrospray mass spectrometry nut procedures soybean Anacardium occidentale Glycine max Juglans Macadamia Arachis Juglans Macadamia Nuts Phospholipids Principal Component Analysis Soybeans Spectrometry, Mass, Electrospray Ionization Triglycerides The probe electrospray ionization (PESI) is an ESI-based ionization technique that generates electrospray from the tip of a solid metal needle. In the present work, we describe the PESI mass spectra obtained by in situ measurement of soybeans and several nuts (peanuts, walnuts, cashew nuts, macadamia nuts and almonds) using different solid needles as sampling probes. It was found that PESI-MS is a valuable approach for in situ lipid analysis of these seeds. The phospholipid and triacylglycerol PESI spectra of different nuts and soybean were compared by principal component analysis (PCA). PCA shows significant differences among the data of each family of seeds. Methanolic extracts of nuts and soybean were exposed to air and sunlight for several days. PESI mass spectra were recorded before and after the treatment. Along the aging of the oil (rancidification), the formation of oxidated species with variable number of hydroperoxide groups could be observed in the PESI spectra. The relative intensity of oxidated triacylglycerols signals increased with days of exposition. Monitoring sensitivity of PESI-MS was high. This method provides a fast, simple and sensitive technique for the analysis (detection and characterization) of lipids in seed tissue and degree of oxidation of the oil samples. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_10765174_v50_n4_p676_Petroselli
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	almonds cashew nuts ESI-MS macadamia nuts peanuts PESI pistachios rancidification walnuts Electrospray ionization Glycerol Ionization Mass spectrometers Mass spectrometry Needles Phospholipids Probes almonds Cashew nut ESI-MS Macadamia nuts peanuts PESI pistachios rancidification walnuts Principal component analysis hydroperoxide methanol phospholipid triacylglycerol phospholipid triacylglycerol acidification aging air almond Article cashew nut comparative study electrospray mass spectrometry lipid analysis lipid composition Macadamia molecular probe molecular weight nut oxidation peanut principal component analysis priority journal probe electrospray ionization mass spectrometry rancidification soybean sunlight walnut Arachis chemistry devices electrospray mass spectrometry nut procedures soybean Anacardium occidentale Glycine max Juglans Macadamia Arachis Juglans Macadamia Nuts Phospholipids Principal Component Analysis Soybeans Spectrometry, Mass, Electrospray Ionization Triglycerides
spellingShingle	almonds cashew nuts ESI-MS macadamia nuts peanuts PESI pistachios rancidification walnuts Electrospray ionization Glycerol Ionization Mass spectrometers Mass spectrometry Needles Phospholipids Probes almonds Cashew nut ESI-MS Macadamia nuts peanuts PESI pistachios rancidification walnuts Principal component analysis hydroperoxide methanol phospholipid triacylglycerol phospholipid triacylglycerol acidification aging air almond Article cashew nut comparative study electrospray mass spectrometry lipid analysis lipid composition Macadamia molecular probe molecular weight nut oxidation peanut principal component analysis priority journal probe electrospray ionization mass spectrometry rancidification soybean sunlight walnut Arachis chemistry devices electrospray mass spectrometry nut procedures soybean Anacardium occidentale Glycine max Juglans Macadamia Arachis Juglans Macadamia Nuts Phospholipids Principal Component Analysis Soybeans Spectrometry, Mass, Electrospray Ionization Triglycerides Petroselli, G. Mandal, M.K. Chen, L.C. Hiraoka, K. Nonami, H. Erra-Balsells, R. In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
topic_facet	almonds cashew nuts ESI-MS macadamia nuts peanuts PESI pistachios rancidification walnuts Electrospray ionization Glycerol Ionization Mass spectrometers Mass spectrometry Needles Phospholipids Probes almonds Cashew nut ESI-MS Macadamia nuts peanuts PESI pistachios rancidification walnuts Principal component analysis hydroperoxide methanol phospholipid triacylglycerol phospholipid triacylglycerol acidification aging air almond Article cashew nut comparative study electrospray mass spectrometry lipid analysis lipid composition Macadamia molecular probe molecular weight nut oxidation peanut principal component analysis priority journal probe electrospray ionization mass spectrometry rancidification soybean sunlight walnut Arachis chemistry devices electrospray mass spectrometry nut procedures soybean Anacardium occidentale Glycine max Juglans Macadamia Arachis Juglans Macadamia Nuts Phospholipids Principal Component Analysis Soybeans Spectrometry, Mass, Electrospray Ionization Triglycerides
description	The probe electrospray ionization (PESI) is an ESI-based ionization technique that generates electrospray from the tip of a solid metal needle. In the present work, we describe the PESI mass spectra obtained by in situ measurement of soybeans and several nuts (peanuts, walnuts, cashew nuts, macadamia nuts and almonds) using different solid needles as sampling probes. It was found that PESI-MS is a valuable approach for in situ lipid analysis of these seeds. The phospholipid and triacylglycerol PESI spectra of different nuts and soybean were compared by principal component analysis (PCA). PCA shows significant differences among the data of each family of seeds. Methanolic extracts of nuts and soybean were exposed to air and sunlight for several days. PESI mass spectra were recorded before and after the treatment. Along the aging of the oil (rancidification), the formation of oxidated species with variable number of hydroperoxide groups could be observed in the PESI spectra. The relative intensity of oxidated triacylglycerols signals increased with days of exposition. Monitoring sensitivity of PESI-MS was high. This method provides a fast, simple and sensitive technique for the analysis (detection and characterization) of lipids in seed tissue and degree of oxidation of the oil samples. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.
format	JOUR
author	Petroselli, G. Mandal, M.K. Chen, L.C. Hiraoka, K. Nonami, H. Erra-Balsells, R.
author_facet	Petroselli, G. Mandal, M.K. Chen, L.C. Hiraoka, K. Nonami, H. Erra-Balsells, R.
author_sort	Petroselli, G.
title	In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
title_short	In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
title_full	In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
title_fullStr	In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
title_full_unstemmed	In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
title_sort	in situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
url	http://hdl.handle.net/20.500.12110/paper_10765174_v50_n4_p676_Petroselli
work_keys_str_mv	AT petrosellig insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry AT mandalmk insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry AT chenlc insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry AT hiraokak insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry AT nonamih insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry AT errabalsellsr insituanalysisofsoybeansandnutsbyprobeelectrosprayionizationmassspectrometry
_version_	1807321618954846208

In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry

Ejemplares similares