Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection
Here we report the derivatization of mesoporous TiO2 thin films for the preparation of H2O2 amperometric sensors. The coordination of the bifunctional ligand 1,10 phenantroline, 5,6 dione on the surface Ti(IV) ions provides open coordination sites for Fe(II) cations which are the starting point for...
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todo:paper_09565663_v26_n2_p890_Gaitan2023-10-03T15:52:09Z Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection Gaitán, M. Gonçales, V.R. Soler-Illia, G.J.A.A. Baraldo, L.M. de Torresi, S.I.C. Amperometric Artificial peroxidase Electrochemical Electrodes Functionalization H2O2 detection Mesoporous Prussian blue Sensor Amperometric Artificial peroxidase Electrochemical Functionalizations H<sub>2</sub>O<sub>2</sub> detection Mesoporous Prussian Blue Amperometric sensors Film preparation Ions Electrochemical electrodes 1,10 phenanthroline 5,6 quinone ferric ferrocyanide ferrous ion hydrogen peroxide phenanthroline derivative polymer titanium dioxide unclassified drug amperometric biosensor article catalysis chemical structure electrochemical detection electrode porosity Biosensing Techniques Catalysis Conductometry Electrodes Equipment Design Equipment Failure Analysis Ferrocyanides Hydrogen Peroxide Porosity Titanium Here we report the derivatization of mesoporous TiO2 thin films for the preparation of H2O2 amperometric sensors. The coordination of the bifunctional ligand 1,10 phenantroline, 5,6 dione on the surface Ti(IV) ions provides open coordination sites for Fe(II) cations which are the starting point for the growth of a layer of Prussian blue polymer. The porous structure of the mesoporous TiO2 allows the growth, ion by ion of the coordination polymer. Up to four layer of Prussian blue can be deposit without losing the porous structure of the film, which results in an enhanced response of these materials as H2O2 sensors. These porous confined PB modified electrodes are robust sensors that exhibit good reproducibility, environmental stability and high sensitivity towards H2O2 detection. © 2010 Elsevier B.V. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baraldo, L.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09565663_v26_n2_p890_Gaitan |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Amperometric Artificial peroxidase Electrochemical Electrodes Functionalization H2O2 detection Mesoporous Prussian blue Sensor Amperometric Artificial peroxidase Electrochemical Functionalizations H<sub>2</sub>O<sub>2</sub> detection Mesoporous Prussian Blue Amperometric sensors Film preparation Ions Electrochemical electrodes 1,10 phenanthroline 5,6 quinone ferric ferrocyanide ferrous ion hydrogen peroxide phenanthroline derivative polymer titanium dioxide unclassified drug amperometric biosensor article catalysis chemical structure electrochemical detection electrode porosity Biosensing Techniques Catalysis Conductometry Electrodes Equipment Design Equipment Failure Analysis Ferrocyanides Hydrogen Peroxide Porosity Titanium |
spellingShingle |
Amperometric Artificial peroxidase Electrochemical Electrodes Functionalization H2O2 detection Mesoporous Prussian blue Sensor Amperometric Artificial peroxidase Electrochemical Functionalizations H<sub>2</sub>O<sub>2</sub> detection Mesoporous Prussian Blue Amperometric sensors Film preparation Ions Electrochemical electrodes 1,10 phenanthroline 5,6 quinone ferric ferrocyanide ferrous ion hydrogen peroxide phenanthroline derivative polymer titanium dioxide unclassified drug amperometric biosensor article catalysis chemical structure electrochemical detection electrode porosity Biosensing Techniques Catalysis Conductometry Electrodes Equipment Design Equipment Failure Analysis Ferrocyanides Hydrogen Peroxide Porosity Titanium Gaitán, M. Gonçales, V.R. Soler-Illia, G.J.A.A. Baraldo, L.M. de Torresi, S.I.C. Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
topic_facet |
Amperometric Artificial peroxidase Electrochemical Electrodes Functionalization H2O2 detection Mesoporous Prussian blue Sensor Amperometric Artificial peroxidase Electrochemical Functionalizations H<sub>2</sub>O<sub>2</sub> detection Mesoporous Prussian Blue Amperometric sensors Film preparation Ions Electrochemical electrodes 1,10 phenanthroline 5,6 quinone ferric ferrocyanide ferrous ion hydrogen peroxide phenanthroline derivative polymer titanium dioxide unclassified drug amperometric biosensor article catalysis chemical structure electrochemical detection electrode porosity Biosensing Techniques Catalysis Conductometry Electrodes Equipment Design Equipment Failure Analysis Ferrocyanides Hydrogen Peroxide Porosity Titanium |
description |
Here we report the derivatization of mesoporous TiO2 thin films for the preparation of H2O2 amperometric sensors. The coordination of the bifunctional ligand 1,10 phenantroline, 5,6 dione on the surface Ti(IV) ions provides open coordination sites for Fe(II) cations which are the starting point for the growth of a layer of Prussian blue polymer. The porous structure of the mesoporous TiO2 allows the growth, ion by ion of the coordination polymer. Up to four layer of Prussian blue can be deposit without losing the porous structure of the film, which results in an enhanced response of these materials as H2O2 sensors. These porous confined PB modified electrodes are robust sensors that exhibit good reproducibility, environmental stability and high sensitivity towards H2O2 detection. © 2010 Elsevier B.V. |
format |
JOUR |
author |
Gaitán, M. Gonçales, V.R. Soler-Illia, G.J.A.A. Baraldo, L.M. de Torresi, S.I.C. |
author_facet |
Gaitán, M. Gonçales, V.R. Soler-Illia, G.J.A.A. Baraldo, L.M. de Torresi, S.I.C. |
author_sort |
Gaitán, M. |
title |
Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
title_short |
Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
title_full |
Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
title_fullStr |
Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
title_full_unstemmed |
Structure effects of self-assembled Prussian blue confined in highly organized mesoporous TiO2 on the electrocatalytic properties towards H2O2 detection |
title_sort |
structure effects of self-assembled prussian blue confined in highly organized mesoporous tio2 on the electrocatalytic properties towards h2o2 detection |
url |
http://hdl.handle.net/20.500.12110/paper_09565663_v26_n2_p890_Gaitan |
work_keys_str_mv |
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