Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina)
The Vendian-Early Cambrian Puncoviscana Formation is a pelite-greywacke turbidite sequence affected by polyphase deformation cropping out extensively in the Cordillera Oriental of northwestern Argentina. Previous X-ray diffraction and analytical high-resolution TEM studies on southern locations foun...
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todo:paper_09351221_v25_n3_p429_DoCampo2023-10-03T15:48:35Z Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) Do Campo, M. Collo, G. Nieto, F. Chlorite, phengite EDX Kübler Index P-T-time paths Scanning electron microscopy Thermobarometry Cambrian chemical composition chlorite diagenesis geobarometry geothermometry metamorphic rock mica mineralogy P-T-t path pelite phengite scanning electron microscopy unconformity Vendian X-ray diffraction Argentina Cordillera Oriental [Argentina] The Vendian-Early Cambrian Puncoviscana Formation is a pelite-greywacke turbidite sequence affected by polyphase deformation cropping out extensively in the Cordillera Oriental of northwestern Argentina. Previous X-ray diffraction and analytical high-resolution TEM studies on southern locations found anchizonal grade and proposed medium-high pressure metamorphism followed by higher thermal conditions. We have determined the chemical composition of mica and chlorite with EDX on small uncontaminated areas selected using SEM in backscattered electron mode. The application of mica-chlorite geothermobarometry to mineral grains defining two different foliations has produced consistent pressure/temperature results based on the intersection of six reactions: 9 kbar/250 °C peak conditions were followed by an isothermal decompression to 3 kbar and a successive increase of temperature to nearly 350 °C at 1.5 kbar. The shales from the overlying Mesón and Santa Victoria Cambro-Ordovician groups do not contain chlorite, thus chlorite-mica geothermobarometry could not be applied. According to the range of KICIS obtained (0.41-0.68Δ°2θ) and their mineralogical assemblage (illite ± kaolinite ± corrensite + Qtz + Pl ± Kfs), these rocks have not surpassed diagenetic conditions, which implies a minimum temperature difference with the Puncoviscana Formation of 100 °C, consistent with the sharp angular unconformity between the two units. © 2013 E. Schweizerbart'sche Verlagsbuchhandlung, D-70176 Stuttgart. Fil:Do Campo, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09351221_v25_n3_p429_DoCampo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Chlorite, phengite EDX Kübler Index P-T-time paths Scanning electron microscopy Thermobarometry Cambrian chemical composition chlorite diagenesis geobarometry geothermometry metamorphic rock mica mineralogy P-T-t path pelite phengite scanning electron microscopy unconformity Vendian X-ray diffraction Argentina Cordillera Oriental [Argentina] |
spellingShingle |
Chlorite, phengite EDX Kübler Index P-T-time paths Scanning electron microscopy Thermobarometry Cambrian chemical composition chlorite diagenesis geobarometry geothermometry metamorphic rock mica mineralogy P-T-t path pelite phengite scanning electron microscopy unconformity Vendian X-ray diffraction Argentina Cordillera Oriental [Argentina] Do Campo, M. Collo, G. Nieto, F. Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
topic_facet |
Chlorite, phengite EDX Kübler Index P-T-time paths Scanning electron microscopy Thermobarometry Cambrian chemical composition chlorite diagenesis geobarometry geothermometry metamorphic rock mica mineralogy P-T-t path pelite phengite scanning electron microscopy unconformity Vendian X-ray diffraction Argentina Cordillera Oriental [Argentina] |
description |
The Vendian-Early Cambrian Puncoviscana Formation is a pelite-greywacke turbidite sequence affected by polyphase deformation cropping out extensively in the Cordillera Oriental of northwestern Argentina. Previous X-ray diffraction and analytical high-resolution TEM studies on southern locations found anchizonal grade and proposed medium-high pressure metamorphism followed by higher thermal conditions. We have determined the chemical composition of mica and chlorite with EDX on small uncontaminated areas selected using SEM in backscattered electron mode. The application of mica-chlorite geothermobarometry to mineral grains defining two different foliations has produced consistent pressure/temperature results based on the intersection of six reactions: 9 kbar/250 °C peak conditions were followed by an isothermal decompression to 3 kbar and a successive increase of temperature to nearly 350 °C at 1.5 kbar. The shales from the overlying Mesón and Santa Victoria Cambro-Ordovician groups do not contain chlorite, thus chlorite-mica geothermobarometry could not be applied. According to the range of KICIS obtained (0.41-0.68Δ°2θ) and their mineralogical assemblage (illite ± kaolinite ± corrensite + Qtz + Pl ± Kfs), these rocks have not surpassed diagenetic conditions, which implies a minimum temperature difference with the Puncoviscana Formation of 100 °C, consistent with the sharp angular unconformity between the two units. © 2013 E. Schweizerbart'sche Verlagsbuchhandlung, D-70176 Stuttgart. |
format |
JOUR |
author |
Do Campo, M. Collo, G. Nieto, F. |
author_facet |
Do Campo, M. Collo, G. Nieto, F. |
author_sort |
Do Campo, M. |
title |
Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
title_short |
Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
title_full |
Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
title_fullStr |
Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
title_full_unstemmed |
Geothermobarometry of very low-grade metamorphic pelites of the Vendian-Early Cambrian Puncoviscana Formation (NW Argentina) |
title_sort |
geothermobarometry of very low-grade metamorphic pelites of the vendian-early cambrian puncoviscana formation (nw argentina) |
url |
http://hdl.handle.net/20.500.12110/paper_09351221_v25_n3_p429_DoCampo |
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