On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel

A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl grou...

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Detalles Bibliográficos
Autores principales: Caballero, G.M., Gros, E.G.
Formato: JOUR
Materias:
Copper(II) Sulphate
Thioacetats
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_09320776_v52_n9_p1147_Caballero
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spelling todo:paper_09320776_v52_n9_p1147_Caballero2023-10-03T15:48:27Z On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel Caballero, G.M. Gros, E.G. Copper(II) Sulphate Thioacetats A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface. Fil:Caballero, G.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Copper(II) Sulphate
Thioacetats
spellingShingle Copper(II) Sulphate
Thioacetats
Caballero, G.M.
Gros, E.G.
On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
topic_facet Copper(II) Sulphate
Thioacetats
description A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface.
format JOUR
author Caballero, G.M.
Gros, E.G.
author_facet Caballero, G.M.
Gros, E.G.
author_sort Caballero, G.M.
title On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_short On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_full On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_fullStr On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_full_unstemmed On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_sort on the mechanism of cleavage of thioacetals promoted by copper(ii) sulphate adsorbed on silica gel
url http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
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