An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter....
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota |
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todo:paper_09320776_v45_n5_p711_BrachetCota2023-10-03T15:48:27Z An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione Brachet-Cota, A.L. Burton, G. 11.19-Oxidopregn-4-ene-3.20-dione 11.19-Oxidoprogesterone 6, 19-Oxido-l 1-ketoprogesterone 6, 19-Oxidopregn-4-ene-3, l 1, 20-trione Synthesis A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter. All rights reserved. Fil:Brachet-Cota, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
11.19-Oxidopregn-4-ene-3.20-dione 11.19-Oxidoprogesterone 6, 19-Oxido-l 1-ketoprogesterone 6, 19-Oxidopregn-4-ene-3, l 1, 20-trione Synthesis |
spellingShingle |
11.19-Oxidopregn-4-ene-3.20-dione 11.19-Oxidoprogesterone 6, 19-Oxido-l 1-ketoprogesterone 6, 19-Oxidopregn-4-ene-3, l 1, 20-trione Synthesis Brachet-Cota, A.L. Burton, G. An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
topic_facet |
11.19-Oxidopregn-4-ene-3.20-dione 11.19-Oxidoprogesterone 6, 19-Oxido-l 1-ketoprogesterone 6, 19-Oxidopregn-4-ene-3, l 1, 20-trione Synthesis |
description |
A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter. All rights reserved. |
format |
JOUR |
author |
Brachet-Cota, A.L. Burton, G. |
author_facet |
Brachet-Cota, A.L. Burton, G. |
author_sort |
Brachet-Cota, A.L. |
title |
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
title_short |
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
title_full |
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
title_fullStr |
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
title_full_unstemmed |
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione |
title_sort |
improved preparation of ll, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione |
url |
http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota |
work_keys_str_mv |
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1807315406815232000 |