An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione

A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter....

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Autores principales: Brachet-Cota, A.L., Burton, G.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota
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spelling todo:paper_09320776_v45_n5_p711_BrachetCota2023-10-03T15:48:27Z An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione Brachet-Cota, A.L. Burton, G. 11.19-Oxidopregn-4-ene-3.20-dione 11.19-Oxidoprogesterone 6, 19-Oxido-l 1-ketoprogesterone 6, 19-Oxidopregn-4-ene-3, l 1, 20-trione Synthesis A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter. All rights reserved. Fil:Brachet-Cota, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 11.19-Oxidopregn-4-ene-3.20-dione
11.19-Oxidoprogesterone
6, 19-Oxido-l 1-ketoprogesterone
6, 19-Oxidopregn-4-ene-3, l 1, 20-trione
Synthesis
spellingShingle 11.19-Oxidopregn-4-ene-3.20-dione
11.19-Oxidoprogesterone
6, 19-Oxido-l 1-ketoprogesterone
6, 19-Oxidopregn-4-ene-3, l 1, 20-trione
Synthesis
Brachet-Cota, A.L.
Burton, G.
An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
topic_facet 11.19-Oxidopregn-4-ene-3.20-dione
11.19-Oxidoprogesterone
6, 19-Oxido-l 1-ketoprogesterone
6, 19-Oxidopregn-4-ene-3, l 1, 20-trione
Synthesis
description A synthesis of 11, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione is described starting from pregn-4-ene-3, 11, 20-trione and via the common intermediate 3β, 20β-diacetyloxy-5α-bromo-6, 19-oxidopregnan-11-one, in 30 and 32% yield, respectively. © 1990, Walter de Gruyter. All rights reserved.
format JOUR
author Brachet-Cota, A.L.
Burton, G.
author_facet Brachet-Cota, A.L.
Burton, G.
author_sort Brachet-Cota, A.L.
title An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
title_short An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
title_full An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
title_fullStr An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
title_full_unstemmed An Improved Preparation of ll, 19-Oxidopregn-4-ene-3, 20-dione and 6, 19-Oxidopregn-4-ene-3, 11, 20-trione
title_sort improved preparation of ll, 19-oxidopregn-4-ene-3, 20-dione and 6, 19-oxidopregn-4-ene-3, 11, 20-trione
url http://hdl.handle.net/20.500.12110/paper_09320776_v45_n5_p711_BrachetCota
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AT brachetcotaal improvedpreparationofll19oxidopregn4ene320dioneand619oxidopregn4ene31120trione
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