Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings

We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two l...

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Autores principales: Capeluto, M.G., Falcione, R., Salvador, R.F., Eceiza, A., Goyanes, S., Ledesma, S.A.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto
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spelling todo:paper_09253467_v90_n_p281_Capeluto2023-10-03T15:46:10Z Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings Capeluto, M.G. Falcione, R. Salvador, R.F. Eceiza, A. Goyanes, S. Ledesma, S.A. Adhesion Azopolymer Functional surfaces Surface relief gratings Electrical engineering Magnetic materials Azopolymer Conformational state Functional surfaces Higher frequencies Interference patterns Molecular ordering Supramolecular architectures Surface relief gratings Adhesion We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Adhesion
Azopolymer
Functional surfaces
Surface relief gratings
Electrical engineering
Magnetic materials
Azopolymer
Conformational state
Functional surfaces
Higher frequencies
Interference patterns
Molecular ordering
Supramolecular architectures
Surface relief gratings
Adhesion
spellingShingle Adhesion
Azopolymer
Functional surfaces
Surface relief gratings
Electrical engineering
Magnetic materials
Azopolymer
Conformational state
Functional surfaces
Higher frequencies
Interference patterns
Molecular ordering
Supramolecular architectures
Surface relief gratings
Adhesion
Capeluto, M.G.
Falcione, R.
Salvador, R.F.
Eceiza, A.
Goyanes, S.
Ledesma, S.A.
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
topic_facet Adhesion
Azopolymer
Functional surfaces
Surface relief gratings
Electrical engineering
Magnetic materials
Azopolymer
Conformational state
Functional surfaces
Higher frequencies
Interference patterns
Molecular ordering
Supramolecular architectures
Surface relief gratings
Adhesion
description We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V.
format JOUR
author Capeluto, M.G.
Falcione, R.
Salvador, R.F.
Eceiza, A.
Goyanes, S.
Ledesma, S.A.
author_facet Capeluto, M.G.
Falcione, R.
Salvador, R.F.
Eceiza, A.
Goyanes, S.
Ledesma, S.A.
author_sort Capeluto, M.G.
title Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
title_short Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
title_full Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
title_fullStr Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
title_full_unstemmed Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
title_sort functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
url http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto
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