Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two l...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto |
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todo:paper_09253467_v90_n_p281_Capeluto2023-10-03T15:46:10Z Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings Capeluto, M.G. Falcione, R. Salvador, R.F. Eceiza, A. Goyanes, S. Ledesma, S.A. Adhesion Azopolymer Functional surfaces Surface relief gratings Electrical engineering Magnetic materials Azopolymer Conformational state Functional surfaces Higher frequencies Interference patterns Molecular ordering Supramolecular architectures Surface relief gratings Adhesion We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Adhesion Azopolymer Functional surfaces Surface relief gratings Electrical engineering Magnetic materials Azopolymer Conformational state Functional surfaces Higher frequencies Interference patterns Molecular ordering Supramolecular architectures Surface relief gratings Adhesion |
spellingShingle |
Adhesion Azopolymer Functional surfaces Surface relief gratings Electrical engineering Magnetic materials Azopolymer Conformational state Functional surfaces Higher frequencies Interference patterns Molecular ordering Supramolecular architectures Surface relief gratings Adhesion Capeluto, M.G. Falcione, R. Salvador, R.F. Eceiza, A. Goyanes, S. Ledesma, S.A. Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
topic_facet |
Adhesion Azopolymer Functional surfaces Surface relief gratings Electrical engineering Magnetic materials Azopolymer Conformational state Functional surfaces Higher frequencies Interference patterns Molecular ordering Supramolecular architectures Surface relief gratings Adhesion |
description |
We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V. |
format |
JOUR |
author |
Capeluto, M.G. Falcione, R. Salvador, R.F. Eceiza, A. Goyanes, S. Ledesma, S.A. |
author_facet |
Capeluto, M.G. Falcione, R. Salvador, R.F. Eceiza, A. Goyanes, S. Ledesma, S.A. |
author_sort |
Capeluto, M.G. |
title |
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
title_short |
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
title_full |
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
title_fullStr |
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
title_full_unstemmed |
Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
title_sort |
functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings |
url |
http://hdl.handle.net/20.500.12110/paper_09253467_v90_n_p281_Capeluto |
work_keys_str_mv |
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