Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina

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The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural...

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Autores principales: Dieuzeide, M.L., de Urtiaga, R., Jobbagy, M., Amadeo, N.
Formato: JOUR
Materias:
1,2-propanediol
CuO catalysts
Glycerol
Hydrogenolysis
Mesoporous alumina.
Alumina
Atmospheric pressure
Catalysts
Copper
Copper oxides
Hydrolysis
Mesoporous materials
X ray diffraction
1 ,2-propanediol
CuO catalyst
Mesoporous alumina
Non-monotonic dependence
Powder X-ray diffraction (pXRD)
Structural characteristics
Temperature-programmed reduction
Textural properties
Catalyst supports
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_09205861_v296_n_p19_Dieuzeide
record_format dspace
spelling todo:paper_09205861_v296_n_p19_Dieuzeide2023-10-03T15:44:57Z Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina Dieuzeide, M.L. de Urtiaga, R. Jobbagy, M. Amadeo, N. 1,2-propanediol CuO catalysts Glycerol Hydrogenolysis Mesoporous alumina. Alumina Atmospheric pressure Catalysts Copper Copper oxides Glycerol Hydrogenolysis Hydrolysis Mesoporous materials X ray diffraction 1 ,2-propanediol CuO catalyst Mesoporous alumina Non-monotonic dependence Powder X-ray diffraction (pXRD) Structural characteristics Temperature-programmed reduction Textural properties Catalyst supports The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural characteristics of the catalysts were determined by N2 sorptometry (BET), powder X-ray diffraction (PXRD), temperature programmed reduction (TPR) and N2O chemisorption (copper metallic area). The characterization showed that all catalysts present textural properties characteristic of mesoporous solids, such as the adsorption isotherms which are type IV. Based both on characterization and activity results, it was possible to conclude that the yield to 1,2-propanediol presented a non-monotonic dependence on total copper metallic area. In addition, it was proved that 1,2-propanediol production is associated with the presence of highly dispersed CuO phase in the solids. Promising results were obtained with CuO(15)Al catalysts, taking into account that the performance can be improved by increasing residence time. © 2017 Elsevier B.V. Fil:Amadeo, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 1,2-propanediol
CuO catalysts
Glycerol
Hydrogenolysis
Mesoporous alumina.
Alumina
Atmospheric pressure
Catalysts
Copper
Copper oxides
Glycerol
Hydrogenolysis
Hydrolysis
Mesoporous materials
X ray diffraction
1 ,2-propanediol
CuO catalyst
Mesoporous alumina
Non-monotonic dependence
Powder X-ray diffraction (pXRD)
Structural characteristics
Temperature-programmed reduction
Textural properties
Catalyst supports
spellingShingle 1,2-propanediol
CuO catalysts
Glycerol
Hydrogenolysis
Mesoporous alumina.
Alumina
Atmospheric pressure
Catalysts
Copper
Copper oxides
Glycerol
Hydrogenolysis
Hydrolysis
Mesoporous materials
X ray diffraction
1 ,2-propanediol
CuO catalyst
Mesoporous alumina
Non-monotonic dependence
Powder X-ray diffraction (pXRD)
Structural characteristics
Temperature-programmed reduction
Textural properties
Catalyst supports
Dieuzeide, M.L.
de Urtiaga, R.
Jobbagy, M.
Amadeo, N.
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
topic_facet 1,2-propanediol
CuO catalysts
Glycerol
Hydrogenolysis
Mesoporous alumina.
Alumina
Atmospheric pressure
Catalysts
Copper
Copper oxides
Glycerol
Hydrogenolysis
Hydrolysis
Mesoporous materials
X ray diffraction
1 ,2-propanediol
CuO catalyst
Mesoporous alumina
Non-monotonic dependence
Powder X-ray diffraction (pXRD)
Structural characteristics
Temperature-programmed reduction
Textural properties
Catalyst supports
description The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural characteristics of the catalysts were determined by N2 sorptometry (BET), powder X-ray diffraction (PXRD), temperature programmed reduction (TPR) and N2O chemisorption (copper metallic area). The characterization showed that all catalysts present textural properties characteristic of mesoporous solids, such as the adsorption isotherms which are type IV. Based both on characterization and activity results, it was possible to conclude that the yield to 1,2-propanediol presented a non-monotonic dependence on total copper metallic area. In addition, it was proved that 1,2-propanediol production is associated with the presence of highly dispersed CuO phase in the solids. Promising results were obtained with CuO(15)Al catalysts, taking into account that the performance can be improved by increasing residence time. © 2017 Elsevier B.V.
format JOUR
author Dieuzeide, M.L.
de Urtiaga, R.
Jobbagy, M.
Amadeo, N.
author_facet Dieuzeide, M.L.
de Urtiaga, R.
Jobbagy, M.
Amadeo, N.
author_sort Dieuzeide, M.L.
title Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
title_short Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
title_full Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
title_fullStr Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
title_full_unstemmed Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
title_sort vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
url http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide
work_keys_str_mv AT dieuzeideml vaporphasehydrogenolysisofglycerolto12propanediolatatmosphericpressureovercoppercatalystssupportedonmesoporousalumina
AT deurtiagar vaporphasehydrogenolysisofglycerolto12propanediolatatmosphericpressureovercoppercatalystssupportedonmesoporousalumina
AT jobbagym vaporphasehydrogenolysisofglycerolto12propanediolatatmosphericpressureovercoppercatalystssupportedonmesoporousalumina
AT amadeon vaporphasehydrogenolysisofglycerolto12propanediolatatmosphericpressureovercoppercatalystssupportedonmesoporousalumina
_version_ 1807323183227863040

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