In-situ catalytic pyrolysis of peanut shells using modified natural zeolite

In-situ catalytic pyrolysis of peanut (Arachis hypogaea) shells was investigated employing modified clinoptilolite. Likewise, conventional pyrolysis of the shells was explored to quantify the deoxygenation degree of bio-oil. Two solid catalysts obtained from natural clinoptilolite were used: one whi...

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Autores principales: Gurevich Messina, L.I., Bonelli, P.R., Cukierman, A.L.
Formato: JOUR
Materias:
Bio-oil quality improvement
Catalytic pyrolysis
Clinoptilolite
Peanut shells
Biofuels
Catalysts
Chemical reactors
Fourier transform infrared spectroscopy
Ion exchange
Oilseeds
Pyrolysis
Scanning electron microscopy
Shells (structures)
Zeolites
Bio oil
Clinoptilolites
Ion-exchange treatment
Modified clinoptilolite
Natural clinoptilolite
Pyridine adsorption
Catalytic cracking
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03783820_v159_n_p160_GurevichMessina
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_03783820_v159_n_p160_GurevichMessina
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spelling todo:paper_03783820_v159_n_p160_GurevichMessina2023-10-03T15:32:18Z In-situ catalytic pyrolysis of peanut shells using modified natural zeolite Gurevich Messina, L.I. Bonelli, P.R. Cukierman, A.L. Bio-oil quality improvement Catalytic pyrolysis Clinoptilolite Peanut shells Biofuels Catalysts Chemical reactors Fourier transform infrared spectroscopy Ion exchange Oilseeds Pyrolysis Scanning electron microscopy Shells (structures) Zeolites Bio oil Catalytic pyrolysis Clinoptilolites Ion-exchange treatment Modified clinoptilolite Natural clinoptilolite Peanut shells Pyridine adsorption Catalytic cracking In-situ catalytic pyrolysis of peanut (Arachis hypogaea) shells was investigated employing modified clinoptilolite. Likewise, conventional pyrolysis of the shells was explored to quantify the deoxygenation degree of bio-oil. Two solid catalysts obtained from natural clinoptilolite were used: one which retained most of the native cations and another one subjected to ion exchange treatment to develop Brønsted acid sites. These catalysts were characterized using different techniques, such as scanning electron microscopy with X-ray microanalysis, Fourier transform infrared spectroscopy by pyridine adsorption, and nitrogen sorptometry. Assays in a bench scale installation based on a fixed bed reactor were conducted at 500 °C and the yields of the three kinds of pyrolysis products (bio-oil, bio-char and gases) were determined. Likewise, the composition and other physical properties of the bio-oil and gases were investigated. Both catalysts led to reduce the oxygen content of the bio-oil, improving its high heating value. On the other hand, catalytic pyrolysis promoted a slight reduction in bio-oil production at expenses of an increase in gases generation. The catalyst subjected to ion exchange performed better than the native form as less water was generated in the catalytic cracking. © 2017 Elsevier B.V. Fil:Bonelli, P.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03783820_v159_n_p160_GurevichMessina
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Bio-oil quality improvement
Catalytic pyrolysis
Clinoptilolite
Peanut shells
Biofuels
Catalysts
Chemical reactors
Fourier transform infrared spectroscopy
Ion exchange
Oilseeds
Pyrolysis
Scanning electron microscopy
Shells (structures)
Zeolites
Bio oil
Catalytic pyrolysis
Clinoptilolites
Ion-exchange treatment
Modified clinoptilolite
Natural clinoptilolite
Peanut shells
Pyridine adsorption
Catalytic cracking
spellingShingle Bio-oil quality improvement
Catalytic pyrolysis
Clinoptilolite
Peanut shells
Biofuels
Catalysts
Chemical reactors
Fourier transform infrared spectroscopy
Ion exchange
Oilseeds
Pyrolysis
Scanning electron microscopy
Shells (structures)
Zeolites
Bio oil
Catalytic pyrolysis
Clinoptilolites
Ion-exchange treatment
Modified clinoptilolite
Natural clinoptilolite
Peanut shells
Pyridine adsorption
Catalytic cracking
Gurevich Messina, L.I.
Bonelli, P.R.
Cukierman, A.L.
In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
topic_facet Bio-oil quality improvement
Catalytic pyrolysis
Clinoptilolite
Peanut shells
Biofuels
Catalysts
Chemical reactors
Fourier transform infrared spectroscopy
Ion exchange
Oilseeds
Pyrolysis
Scanning electron microscopy
Shells (structures)
Zeolites
Bio oil
Catalytic pyrolysis
Clinoptilolites
Ion-exchange treatment
Modified clinoptilolite
Natural clinoptilolite
Peanut shells
Pyridine adsorption
Catalytic cracking
description In-situ catalytic pyrolysis of peanut (Arachis hypogaea) shells was investigated employing modified clinoptilolite. Likewise, conventional pyrolysis of the shells was explored to quantify the deoxygenation degree of bio-oil. Two solid catalysts obtained from natural clinoptilolite were used: one which retained most of the native cations and another one subjected to ion exchange treatment to develop Brønsted acid sites. These catalysts were characterized using different techniques, such as scanning electron microscopy with X-ray microanalysis, Fourier transform infrared spectroscopy by pyridine adsorption, and nitrogen sorptometry. Assays in a bench scale installation based on a fixed bed reactor were conducted at 500 °C and the yields of the three kinds of pyrolysis products (bio-oil, bio-char and gases) were determined. Likewise, the composition and other physical properties of the bio-oil and gases were investigated. Both catalysts led to reduce the oxygen content of the bio-oil, improving its high heating value. On the other hand, catalytic pyrolysis promoted a slight reduction in bio-oil production at expenses of an increase in gases generation. The catalyst subjected to ion exchange performed better than the native form as less water was generated in the catalytic cracking. © 2017 Elsevier B.V.
format JOUR
author Gurevich Messina, L.I.
Bonelli, P.R.
Cukierman, A.L.
author_facet Gurevich Messina, L.I.
Bonelli, P.R.
Cukierman, A.L.
author_sort Gurevich Messina, L.I.
title In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
title_short In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
title_full In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
title_fullStr In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
title_full_unstemmed In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
title_sort in-situ catalytic pyrolysis of peanut shells using modified natural zeolite
url http://hdl.handle.net/20.500.12110/paper_03783820_v159_n_p160_GurevichMessina
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AT bonellipr insitucatalyticpyrolysisofpeanutshellsusingmodifiednaturalzeolite
AT cukiermanal insitucatalyticpyrolysisofpeanutshellsusingmodifiednaturalzeolite
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